Bicyclo[6.1.0]nonane

Base Information

• Chemical Name: Bicyclo[6.1.0]nonane
• CAS No.: 286-60-2
• Molecular Formula: C9H16
• Molecular Weight: 124.226
• Hs Code.: 2902199090
• Mol file: 286-60-2.mol

Synonyms:

Chemical Property of Bicyclo[6.1.0]nonane

Chemical Property:

• Vapor Pressure: 2.35mmHg at 25°C
• Boiling Point: 166.5°Cat760mmHg
• Flash Point: 37.3°C
• PSA: 0.00000
• Density: 0.882g/cm³
• LogP: 2.97670

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of Bicyclo[6.1.0]nonane

There total 11 articles about Bicyclo[6.1.0]nonane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

C8H14CH2PtCl2(C5H5N)2 → cis-Cyclooctene (931-88-4,931-87-3,25267-51-0) + bicyclo[6.1.0]nonane (286-60-2) + methylenecyclooctane (3618-18-6) + 1-methylcyclooctene (15840-64-9)

Guidance literature:

With diazomethane; In chloroform; addn. of a large excess of CH2N2 via a stream of N2; vac. distn.; detn. by NMR, chromy.;

DOI:10.1021/ja00247a023

Reference yield:

tetramethylammonium trifluoromethanesulphonate (25628-09-5) + 1,2-cyclooctene (931-88-4,22770-27-0,3958-30-3,25267-51-0) → bicyclo[6.1.0]nonane (286-60-2) + cyclopropane (75-19-4)

Guidance literature:

With dibromobis(triphenylphosphine)nickel(II); n-butyllithium; In tetrahydrofuran; hexane; at 0 - 20 ℃; for 16h; Reagent/catalyst; Concentration; Inert atmosphere; Schlenk technique;

DOI:10.1002/anie.201505482

Reference yield:

(+)-(1S,8S)trans-9,9-Dibrombicyclo<6.1.0.>nonan (26216-40-0) → trans-Bicyclo<6.1.0>nonan (286-60-2,13757-43-2,20480-43-7,39124-79-3)

Guidance literature:

With ammonia; sodium;

DOI:10.1021/ja00748a059

upstream raw materials:

9,9-dichlorobicyclo<6.1.0>nonane

bicyclo<6.1.0>nona-1,6-diene

8-methylenebicyclo<5.1.0>oct-2-ene

8-methyl-8-chlorobicyclo<5.1.0>oct-2-ene

Downstream raw materials:

bicyclo<6.1.0>nonan-2-one

methylcyclooctane

Acetic acid (1R,4S)-4-methyl-cyclooctyl ester

Spiro<2.7>decan-4-one

Refernces

• 1、 Mil'vitskaya, E. M.,Pekhk, T. I.,Pereslegina, N. S.,Tarakanova, A. V.,Ivanov, A. V.. "SYNTHESIS AND THERMAL TRANSFORMATIONS OF BICYCLOALKENES CONTAINING A METHYLENECYCLOPROPANE FRAGMENT". . p. 1573 - 1583. Retrieved 2007/10/02.