Methyl phenanthrene-3-carboxylate

Base Information

• Chemical Name: Methyl phenanthrene-3-carboxylate
• CAS No.: 5345-98-2
• Molecular Formula: C₁₆H₁₂O₂
• Molecular Weight: 236.27
• Hs Code.: 2916399090
• Mol file: 5345-98-2.mol

Synonyms:Methyl3-phenanthrenecarboxylate; Methyl 3-phenanthroate; NSC 1776

Chemical Property of Methyl phenanthrene-3-carboxylate

Chemical Property:

• Vapor Pressure: 8.81E-07mmHg at 25°C
• Refractive Index: 1.677
• Boiling Point: 405.4 °C at 760mmHg
• Flash Point: 194.3 °C
• PSA: 26.30000
• Density: 1.208 g/cm³
• LogP: 3.77960
• Storage Temp.: 2-8°C

Purity/Quality:

99% ^*data from raw suppliers

Methylphenanthrene-3-carboxylate 95+% ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of Methyl phenanthrene-3-carboxylate

There total 10 articles about Methyl phenanthrene-3-carboxylate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 81.0%

1-(4-methoxycarbonylphenyl)-2-phenylethene (17404-87-4) → methyl 3-phenanthrenecarboxylate (5345-98-2)

Guidance literature:

With potassium iodide; In cyclohexane; for 3.5h; Irradiation;

DOI:10.1021/acs.joc.6b01450

Reference yield:

1,3-dihydro-1-hydroxynaphtho<1,2-c>furan (89005-09-4) + acrylic acid methyl ester (292638-85-8,9003-21-8,96-33-3) → methyl 3-phenanthrenecarboxylate (5345-98-2) + methyl phenanthrene-2-carboxylate (25308-63-8)

Guidance literature:

With hydrogenchloride; trichloroacetic acid; Multistep reaction. Title compound not separated from byproducts; 1.) reflux, 1 h, 2.) MeOH, reflux, 30 min;

DOI:10.1021/jo00248a009

Reference yield:

methanol (67-56-1) → methyl 3-phenanthrenecarboxylate (5345-98-2)

Guidance literature:

With sulfuric acid;

DOI:10.3758/BF03194964

upstream raw materials:

methanol

1,2,3,4-tetrahydro-phenanthrene-3-carboxylic acid

phenantrene-3-carboxylic acid chloride

1,3-dihydro-1-hydroxynaphtho<1,2-c>furan

Downstream raw materials:

phenanthrene-3-carboxylic acid

Refernces

• 1、 Matsushima, Tomoya,Kobayashi, Sayaka,Watanabe, Soichiro. "Air-Driven Potassium Iodide-Mediated Oxidative Photocyclization of Stilbene Derivatives". . p. 7799 - 7806. Retrieved 2016/09/09.