(Diphenylphosphonimido)triphenylphosphorane

Base Information

• Chemical Name: (Diphenylphosphonimido)triphenylphosphorane
• CAS No.: 2156-69-6
• Molecular Formula: C30H25 N O P2
• Molecular Weight: 477.482
• Hs Code.: 2931900090
• European Community (EC) Number: 800-063-1
• NSC Number: 76071
• DSSTox Substance ID: DTXSID70944164
• Nikkaji Number: J85.584G
• Wikidata: Q82921358
• Mol file: 2156-69-6.mol

Synonyms:2156-69-6;(Diphenylphosphonimido)triphenylphosphorane;diphenylphosphorylimino(triphenyl)-$l^{5}-phosphane;diphenylphosphorylimino(triphenyl)-lambda5-phosphane;NSC76071;p,p-diphenyl-n-(triphenylphosphoranylidene)phosphinic amide;DIPHENYLPHOSPHONIMIDOTRIPHENYLPHOSPHORANE;SCHEMBL13123153;DTXSID70944164;NSC-76071;AKOS025396906;P,P-Diphenyl-N-(triphenyl-lambda~5~-phosphanylidene)phosphinic amide

Chemical Property of (Diphenylphosphonimido)triphenylphosphorane

Chemical Property:

• Vapor Pressure: 7.08E-15mmHg at 25°C
• Melting Point: 170-174°C
• Boiling Point: 625.3°C at 760 mmHg
• Flash Point: 332°C
• PSA: 49.05000
• Density: 1.14g/cm³
• LogP: 6.09320
• Water Solubility.: Insoluble in water.
• XLogP3: 7.4
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 2
• Rotatable Bond Count: 6
• Exact Mass: 477.14113842
• Heavy Atom Count: 34
• Complexity: 644

Purity/Quality:

99% ^*data from raw suppliers

(DIPHENYL PHOSPHONIMIDO)TRIPHENYLPHOSPHORANE 95.00% ^*data from reagent suppliers

Safty Information:

• Safety Statements: 22-24/25

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C1=CC=C(C=C1)P(=NP(=O)(C2=CC=CC=C2)C3=CC=CC=C3)(C4=CC=CC=C4)C5=CC=CC=C5
• Uses: (Diphenylphosphonimido)triphenylphosphorane is used as a ligand and form coordination complexes with metal ions in synthetic chemistry.

Technology Process of (Diphenylphosphonimido)triphenylphosphorane

There total 8 articles about (Diphenylphosphonimido)triphenylphosphorane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 95.0%

lithium triphenylphosphonium azayldiide (13916-35-3) + Diphenylphosphinic chloride (1499-21-4) → N-(diphenylphosphinyl)triphenylphospha-λ5-azene (2156-69-6)

Guidance literature:

Reference yield: 85.0%

lithium triphenylphosphonium azayldiide (13916-35-3) + chloro-diphenylphosphine (1079-66-9,74391-44-9) → N-(diphenylphosphinyl)triphenylphospha-λ5-azene (2156-69-6)

Guidance literature:

lithium triphenylphosphonium azayldiide; chloro-diphenylphosphine; In tetrahydrofuran; at 20 ℃; for 0.5h;

With dihydrogen peroxide; In tetrahydrofuran; Further stages.;

DOI:10.1016/j.tet.2008.05.019

Reference yield: 76.0%

diphenylphosphinamide (5994-87-6) + triphenylphosphine (603-35-0) → N-(diphenylphosphinyl)triphenylphospha-λ5-azene (2156-69-6)

Guidance literature:

With diethylazodicarboxylate; In tetrahydrofuran; at 0 - 25 ℃; for 24h;

DOI:10.1021/jo00210a027

upstream raw materials:

diphenylphosphoranyl azide

triphenylphosphine

diphenylphosphinamide

lithium triphenylphosphonium azayldiide

Downstream raw materials:

W(CO)5(OP(C₆H₅)2NP(C₆H₅)3)

Refernces

• 1、 -. "Fluorescent compounds". . . Retrieved 2008/06/13.
• 2、 Cristeau, Henri-Jean,Manginot, Eric,Torreilles, Eliane. "PHOSPHONIUM AZA-YLDIID AS REAGENT FOR ONE-POT SYNTHESIS OF PHOSPHINIMINES WITH FUNCTIONAL N-SUBSTITUENTS.". . p. 347 - 350. Retrieved 2007/10/02.