Zincum iodatum

Base Information

• Chemical Name: Zincum iodatum
• CAS No.: 10139-47-6
• Molecular Formula: I₂Zn
• Molecular Weight: 319.199
• Hs Code.: 2827600000
• UNII: 762R7A0O0B
• Nikkaji Number: J44.260G
• Wikidata: Q204828
• Mol file: 10139-47-6.mol

Synonyms:zinc(II)iodide;zinc (II) iodide;ZINCUM IODATUM;ZnI2;ZINC IODIDE [MI];ZINC IODIDE [WHO-DD];ZINCUM IODATUM [HPUS];UAYWVJHJZHQCIE-UHFFFAOYSA-L;AKOS015833261;Q204828

Chemical Property of Zincum iodatum

Chemical Property:

• Appearance/Colour: White crystalline powder
• Melting Point: 445 °C(lit.)
• Boiling Point: 624 °C
• Flash Point: 625°C
• PSA: 0.00000
• Density: 4.74 g/mL at 25 °C(lit.)
• LogP: 1.76890
• Water Solubility.: 333 g/100 mL
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 2
• Rotatable Bond Count: 0
• Exact Mass: 317.73809
• Heavy Atom Count: 3
• Complexity: 0

Purity/Quality:

98% ^*data from raw suppliers

Safty Information:

• Pictogram(s): C
• Hazard Codes: C:Corrosive
• Statements: R34:
• Safety Statements: S26:; S36/37/39:; S45:

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

• Canonical SMILES: [Zn+2].[I-].[I-]

Technology Process of Zincum iodatum

There total 23 articles about Zincum iodatum which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 50.0%

bis[tris(trimethylsilyl)germyl]zinc + methyl iodide (74-88-4) → methyltris(trimethylsilyl)germane (404888-68-2) + zinc(II) iodide (10139-47-6)

Guidance literature:

In diethyl ether; under Ar; stirring in Et2O at room temp. for 3 days; products identified by GC, GC-MS, and NMR;

DOI:10.1246/bcsj.76.1261

Reference yield:

hydrogen iodide (10034-85-2) + zinc(II) carbonate (743369-26-8) → zinc(II) iodide (10139-47-6)

Guidance literature:

In further solvent(s); dissolved in HI;;

Reference yield:

iodine (7553-56-2,12190-71-5,8031-47-8) + zinc (7440-66-6) → zinc(II) iodide (10139-47-6)

Guidance literature:

In N,N-dimethyl acetamide;

upstream raw materials:

iodine

zinc

hydrogen iodide

zinc(II) carbonate

Downstream raw materials:

triiodide^(1-)

tetraiodomercurate(II)^(2-)

C₆H₅C(OC₂H₅)CHZnI₂

zinc(II) (3,4-dimethoxybenzaldehyde thiosemicarbazone)2 diiodide

Refernces

• 1、 Jiang, Yan-Si,Yao, Hua-Gang,Ji, Shou-Hua,Ji, Min,An, Yong-Lin. "New framework lodoargentates: M(en)3Ag2I4 (M = Zn, Ni) with tridymite topology". . p. 3922 - 3924. Retrieved 2008.
• 2、 Blachnik, R.,Stoeter, U.. "-". . p. 115 - 122. Retrieved 1989.
• 3、 Xi, Chanjuan,Sun, Zelin,Liu, Yongbing. "Cyclotrimerization of terminal alkynes catalyzed by the system of NiCl 2/Zn and (benzimidazolyl)-6-(1-(arylimino)ethyl)pyridines". . p. 13327 - 13330. Retrieved 2013.
• 4、 Wriedt, Mario,Jess, Inke,Naether, Christian. "Synthesis, crystal structures, and thermal properties of new [ZnX 2(2,5-dimethylpyrazine)] (X = Cl, Br, I) coordination compounds". . p. 363 - 372. Retrieved 2009.
• 5、 Moriya, Kohei,Simon, Meike,Mose, Rasmus,Karaghiosoff, Konstantin,Knochel, Paul. "Stereoselective Retentive Domino Transmetalations of Secondary Alkyllithium Compounds to Functionalized Secondary Alkylcopper Reagents". supporting information. p. 10963 - 10967. Retrieved 2015/09/15.
• 6、 Yestrepsky, Bryan D.,Xu, Yuanxi,Breen, Meghan E.,Li, Xiaoqin,Rajeswaran, Walajapet G.,Ryu, Jenny G.,Sorenson, Roderick J.,Tsume, Yasuhiro,Wilson, Michael W.,Zhang, Wenpeng,Sun, Duxin,Sun, Hongmin,Larsen, Scott D.. "Novel inhibitors of bacterial virulence: Development of 5,6-dihydrobenzo[h]quinazolin-4(3H)-ones for the inhibition of group A streptococcal streptokinase expression". . p. 1880 - 1897. Retrieved 2013/05/08.