cyclohexatrienylimino-triphenyl-phosphorane; palladium; N,N,N,N-tetramethylethane-1,2-diamine; triphenylphosphanium

Base Information

• Chemical Name: cyclohexatrienylimino-triphenyl-phosphorane; palladium; N,N,N,N-tetramethylethane-1,2-diamine; triphenylphosphanium
• CAS No.: 7236-88-6
• Molecular Formula: C₁₇H₂₂NO₃P
• Molecular Weight: 319.34
• Mol file: 7236-88-6.mol

Synonyms:

Chemical Property of cyclohexatrienylimino-triphenyl-phosphorane; palladium; N,N,N,N-tetramethylethane-1,2-diamine; triphenylphosphanium

Chemical Property:

• Boiling Point: 505.3°Cat760mmHg
• Flash Point: 259.4°C
• PSA: 57.37000
• Density: g/cm³
• LogP: 5.13640

Purity/Quality:

99% ^*data from raw suppliers

Diethyl(phenyl(phenylamino)methyl)phosphonate 97% ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of cyclohexatrienylimino-triphenyl-phosphorane; palladium; N,N,N,N-tetramethylethane-1,2-diamine; triphenylphosphanium

There total 41 articles about cyclohexatrienylimino-triphenyl-phosphorane; palladium; N,N,N,N-tetramethylethane-1,2-diamine; triphenylphosphanium which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

benzaldehyde (100-52-7) + aniline (62-53-3) + phosphonic acid diethyl ester (762-04-9) → diethyl[anilino(phenyl)methyl]phosphonate (68374-69-6,7236-88-6)

Guidance literature:

With tin(ll) chloride; at 20 ℃; for 0.5h; under 760.051 Torr; neat (no solvent);

DOI:10.1055/s-0029-1217091

Reference yield: 99.0%

benzylidene phenylamine (538-51-2) + phosphonic acid diethyl ester (762-04-9) → diethyl[anilino(phenyl)methyl]phosphonate (68374-69-6,7236-88-6)

Guidance literature:

With C₄₂H₇₄LiN₆Si₄Yb; In tetrahydrofuran; at 40 ℃; for 6h; Inert atmosphere;

DOI:10.1021/ic300137r

Reference yield: 99.0%

benzaldehyde (100-52-7) + aniline (62-53-3) + triethyl phosphite (122-52-1) → diethyl[anilino(phenyl)methyl]phosphonate (68374-69-6,7236-88-6)

Guidance literature:

With cerium(IV) oxide; for 0.0833333h; Sonication; Neat (no solvent);

DOI:10.1016/j.tetlet.2011.04.112

upstream raw materials:

(N-phenyl-benzimidoyl)-phosphonic acid diethyl ester

benzylidene phenylamine

phosphonic acid diethyl ester

triethyl phosphite

Downstream raw materials:

C₃₄H₂₆NO₃P

(α-anilinobenzyl)phosphonic acid monoethyl ester

N-Acetyl-α-anilinobenzyl-phosphorige Saeure

Refernces

• 1、 Gholivand, Khodayar,Abbod, Mohsen,Ebrahimi Valmoozi, Ali Asghar,Barzegar, Omolbanin,Nasrollah Tabar, Hadis,Yaghoubi, Rouhollah,Hosseini, Mahdieh,Safaie, Naser,Rahimzadeh Dashtaki, Maryam,Dusek, Michal,Mani-Varnosfaderani, Ahmad. "Synthesis and crystal structure of phosphonic acid and bisphosphoramidate derivatives: QSAR studies of their anti-fungal potential on Macrophomina Phaseolina (Tassi) Goid". . p. 1591 - 1606. Retrieved 2021/01/07.
• 2、 Sajadi, S Mohammad. "Magnetic ZnO?CuO?Iron ore nanocomposites as a green and highly efficient heterogeneous nanocatalyst for solventless synthesis of α-aminophosphonates". . p. 25 - 30. Retrieved 2019/11/14.