Ytterbium trifluoride

Base Information

• Chemical Name: Ytterbium trifluoride
• CAS No.: 13760-80-0
• Molecular Formula: F3Yb
• Molecular Weight: 230.035
• Hs Code.: 28261990
• European Community (EC) Number: 237-354-2
• DSSTox Substance ID: DTXSID3065613
• Wikipedia: Ytterbium trifluoride,Ytterbium(III) fluoride,Ytterbium(III)_fluoride
• Wikidata: Q16933
• Mol file: 13760-80-0.mol

Synonyms:Ytterbium(III) fluoride;Ytterbium trifluoride;EINECS 237-354-2;DTXSID3065613;Ytterbium fluoride, granular, <=1.6 mm;LS-162770;Ytterbium(III) fluoride, anhydrous, REacton?;Q16933;Ytterbium(III) fluoride (99.9%-Yb) (REO);Barium Manganese Oxide (BMO) Sputtering Targets;Ytterbium(III) fluoride, anhydrous, powder, 99.98% trace metals basis

Chemical Property of Ytterbium trifluoride

Chemical Property:

• Appearance/Colour: white to off-white powder
• Melting Point: 1157 °C
• Refractive Index: 1.54
• Boiling Point: 2200 °C
• PSA: 0.00000
• Density: 4.01 g/mL at 25 °C(lit.)
• LogP: -8.98800
• Sensitive.: Hygroscopic
• Water Solubility.: Soluble moderately in strong mineral acids. Insoluble in water.
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 3
• Rotatable Bond Count: 0
• Exact Mass: 230.9340770
• Heavy Atom Count: 4
• Complexity: 8

Purity/Quality:

99.9% ^*data from raw suppliers

Ytterbium(III) fluoride, anhydrous 99.9% ^*data from reagent suppliers

Safty Information:

• Pictogram(s): T,Xi
• Hazard Codes: T,Xi
• Statements: 23/24/25-32
• Safety Statements: 26-36/37/39-45

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

• Canonical SMILES: F[Yb](F)F
• Uses: Ytterbium Fluoride is applied to numerous fiber amplifier and fiber optic technologies, High purity grades are widely applied as a doping agent for garnet crystals in lasers a important colourant in glasses and porcelain enamel glazes. Ytterbium Fluoride is a water insoluble Ytterbium source for use in oxygen-sensitive applications, such as metal production. Ytterbium Fluoride is a useful compound in the manufacturing process of aluminum nitride powder.

Technology Process of Ytterbium trifluoride

There total 36 articles about Ytterbium trifluoride which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

ytterbium(III) oxide + hydrogen fluoride (7664-39-3,12381-92-9,32057-09-3,74835-82-8) → ytterbium(III) fluoride (13760-80-0)

Guidance literature:

In neat (no solvent); byproducts: H2O; at elevated temp.;;

DOI:10.1021/ja02222a009 DOI:10.1007/BF01481992

Reference yield:

ytterbium(III) oxide + ammonium fluoride → ytterbium(III) fluoride (13760-80-0)

Guidance literature:

In hydrogenchloride; dissolving oxide in aq. HCl, pptn. with excess aq. NH4F, filtration, drying, dehydration on heating ppt. with excess powdered NH4F to 360°C in a dry stream of He or Ne (O2-free) for 5h;;

Reference yield:

ytterbium(III) oxide + chlorine trifluoride (7790-91-2) → ytterbium(III) fluoride (13760-80-0)

Guidance literature:

In neat (no solvent); at room temp. in presence of moisture;;

DOI:10.1021/ja01644a016

upstream raw materials:

benzyl fluoride

sodium fluoride

sulfuric acid

xenon difluoride

Downstream raw materials:

terbium tetrafluoride

ytterbium(III) oxyfluoride

ytterbium telluride

ytterbium monofluoride

Refernces

• 1、 Poulain,Tofield. "STRUCTURE OF CUBIC YbZrF7.". . p. 314 - 328. Retrieved 1981.
• 2、 Biefeld, R. M.,Eick, H. A.. "". . p. 1190 - 1197. Retrieved 1975.
• 3、 Patterson, Wendy M.,Stark, Peter C.,Yoshida, Thomas M.,Sheik-Bahae, Mansoor,Hehlen, Markus P.. "Preparation and characterization of high-purity metal fluorides for photonic applications". . p. 2896 - 2901. Retrieved 2011/12/22.
• 4、 Du, Ya-Ping,Zhang, Ya-Wen,Sun, Ling-Dong,Yan, Chun-Hua. "Optically active uniform potassium and lithium rare earth fluoride nanocrystals derived from metal trifluroacetate precursors". . p. 8574 - 8581. Retrieved 2011/01/06.