Diethylmercury

Base Information

• Chemical Name: Diethylmercury
• CAS No.: 627-44-1
• Molecular Formula: C4H10 Hg
• Molecular Weight: 258.713
• Hs Code.: 2931900090
• European Community (EC) Number: 211-000-7
• UNII: 323TG9BTE8
• DSSTox Substance ID: DTXSID1060841
• Wikipedia: Diethylmercury
• Wikidata: Q2503726
• Mol file: 627-44-1.mol

Synonyms:diethyl mercury;diethylmercury

Chemical Property of Diethylmercury

Chemical Property:

• Melting Point: -91.7°C
• Boiling Point: 56-57°C 20mm
• PSA: 0.00000
• Density: 2,446 g/cm3
• LogP: 1.94530
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 0
• Rotatable Bond Count: 0
• Exact Mass: 260.048894
• Heavy Atom Count: 5
• Complexity: 11.1

Purity/Quality:

Safty Information:

• Statements: 26/27/28-33
• Safety Statements: 13-28-36-45

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CC[Hg]CC

Technology Process of Diethylmercury

There total 55 articles about Diethylmercury which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

ethylmagnesium bromide (925-90-6) + pentafluorophenylmercury chloride (941-78-6) → Pentafluorobenzene (363-72-4) + diethylmercury (627-44-1) + bis(pentafluorophenyl)mercury(II) (973-17-1) + (pentafluoro phenyl) ethyl mercury

Guidance literature:

In tetrahydrofuran; diethyl ether; at 22 ℃; Inert atmosphere;

DOI:10.1134/S1070363219070090

Reference yield:

ethyllithium (811-49-4) + diphenylmercury(II) (587-85-9,1337-09-3) → diethylmercury (627-44-1) + phenyllithium (591-51-5)

Guidance literature:

Reference yield:

diethylzinc (557-20-0) + allylmercuric iodide (2845-00-3) → 1,5-Hexadien (592-42-7) + diethylmercury (627-44-1)

Guidance literature:

upstream raw materials:

ethylmagnesium iodide

ethyl bromide

diethyl sulfate

triethyl borane

Downstream raw materials:

2-methyl-2-phenylpropionic acid

diphenylmercury(II)

ethylmercury ⁽¹⁺⁾; iodide

diethylphenylarsine

Refernces

• 1、 Schlesinger,Brown. "-". . p. 3429,3433,3435. Retrieved 1940.
• 2、 Hale, C. F.,Nunez, V. E.. "". . p. 1555. Retrieved 1911.
• 3、 Dunn, Philip J.H.,Bilsel, Mine,?im?ek, Adnan,G?ren, Ahmet Ceyhan,Tun?, Murat,Ogrinc, Nives,Horvat, Milena,Goenaga-Infante, Heidi. "Practical and theoretical considerations for the determination of δ13CVPDB values of methylmercury in the environment". . p. 1122 - 1136. Retrieved 2019/06/24.
• 4、 Banerjee, Mainak,Karri, Ramesh,Chalana, Ashish,Das, Ranajit,Rai, Rakesh Kumar,Rawat, Kuber Singh,Pathak, Biswarup,Roy, Gouriprasanna. "Protection of Endogenous Thiols against Methylmercury with Benzimidazole-Based Thione by Unusual Ligand-Exchange Reactions". supporting information. p. 5696 - 5707. Retrieved 2017/04/28.