nitrosomethane

Base Information

• Chemical Name: nitrosomethane
• CAS No.: 865-40-7
• Molecular Formula: CH3 N O
• Molecular Weight: 45.0409
• Hs Code.: 2904209090
• Mol file: 865-40-7.mol

Synonyms:Nitrosomethane

Chemical Property of nitrosomethane

Chemical Property:

• Vapor Pressure: 3330mmHg at 25°C
• Boiling Point: -18.3±9.0 °C(Predicted)
• PSA: 29.43000
• Density: 0.93g/cm³
• LogP: 0.38260

Purity/Quality:

99%, ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of nitrosomethane

There total 6 articles about nitrosomethane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

di-tert-butyl peroxide (110-05-4) → tert.-butylnitrite (540-80-7) + nitrosomethane (865-40-7) + ethane (74-84-0) + acetone (67-64-1)

Guidance literature:

at 160 ℃; Mechanism; zeitlicher Verlauf_.Pyrolysis;

Reference yield:

methyl radical (2229-07-4) → nitrosomethane (865-40-7) + ethane (74-84-0)

Guidance literature:

With nitrogen(II) oxide; In gas; at 22.9 ℃; under 25.1 Torr; Rate constant; Kinetics; other pressures, other temperatures;

DOI:10.1039/ft9918702317

Reference yield:

methane (34557-54-5,27936-85-2) → methylene chloride (74-87-3) + nitrosomethane (865-40-7) + dichloromethane (75-09-2)

Guidance literature:

With nitrogen(II) oxide; chlorine; at -9.1 - 96.9 ℃; under 3 - 11000 Torr; Rate constant; Irradiation; investigated the pressure dependence on one temperature: and in different diluente;

DOI:10.1021/j100147a022

upstream raw materials:

tert.-butylnitrite

i-propyl nitrite

methyl radical

methane

Downstream raw materials:

formaldoxime

N-methyl-C-(N-phenylcarbamoyl)nitrone

Refernces

• 1、 Davies, Joanne W.,Green, Nicholas J. B.,Pilling, Michael J.. "Association Reaction of CH3 and NO: Evidence for the Involvement of the Triplet Surface". . p. 2317 - 2324. Retrieved 2007/10/02.