2-hydroperoxyheptane

Base Information

• Chemical Name: 2-hydroperoxyheptane
• CAS No.: 762-46-9
• Molecular Formula: C7H16 O2
• Molecular Weight: 132.203
• Mol file: 762-46-9.mol

Synonyms:2-Heptylhydroperoxide; 2-Hydroperoxyheptane

Chemical Property of 2-hydroperoxyheptane

Chemical Property:

• Vapor Pressure: 0.103mmHg at 25°C
• Boiling Point: 196.3°C at 760 mmHg
• Flash Point: 72.5°C
• PSA: 29.46000
• Density: 0.891g/cm³
• LogP: 2.44480

Purity/Quality:

99%, ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of 2-hydroperoxyheptane

There total 3 articles about 2-hydroperoxyheptane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

n-heptane (142-82-5) → n-pentyl methyl ketone (110-43-0) + 1-methylhexyl-hydroperoxide (762-46-9) + 1-heptyl hydroperoxide (764-81-8,51728-68-8) + 3-heptyl hydroperoxide (761-70-6) + 4-heptyl hydroperoxide (761-40-0) + heptan-3-one (106-35-4)

Guidance literature:

With 2-pyrazylcarboxylic acid; dihydrogen peroxide; oxygen; [n-Bu₄N]VO₃; In acetonitrile; at 23 ℃; for 24h; Product distribution; Mechanism; other alkanes; var. time, with or without H₂O and irradiation;

DOI:10.1016/0040-4020(96)00769-7

Reference yield:

n-heptane (142-82-5) → 1-methylhexyl-hydroperoxide (762-46-9) + 1-heptyl hydroperoxide (764-81-8,51728-68-8) + 3-heptyl hydroperoxide (761-70-6) + 4-heptyl hydroperoxide (761-40-0)

Guidance literature:

With air; dihydrogen peroxide; 2-pyrazylcarboxylic acid; [n-Bu₄N]VO₃; In water; acetonitrile; at 23 ℃; for 3h; Further byproducts given;

DOI:10.1007/BF02495206

Reference yield:

n-heptane (142-82-5) → 1-methylhexyl-hydroperoxide (762-46-9) + 3-heptyl hydroperoxide (761-70-6) + 4-heptyl hydroperoxide (761-40-0)

Guidance literature:

at 130 ℃; under 2206.5 Torr;

DOI:10.1177/107110070202300608

upstream raw materials:

n-heptane

Downstream raw materials:

n-pentyl methyl ketone

heptan-2-yl acetate

2-Heptanol

2-chloroheptane

Refernces

• 1、 Shul'pin, Georgiy B.,Kozlov, Yuriy N.,Nizova, Galina V.,Suess-Fink, Georg,Stanislas, Sandrine,Kitaygorodskiy, Alex,Kulikova, Vera S.. "Oxidations by the reagent "O2-H2O2-vanadium derivative-pyrazine-2-carboxylic acid". Part 12. Main features, kinetics and mechanism of alkane hydroperoxidation". . p. 1351 - 1371. Retrieved 2007/10/03.
• 2、 Shul'pin, Georgiy B.,Guerreiro, Mario C.,Schuchardt, Ulf. "Oxidations by the reagent O2-H2O2-vanadium complex - Pyrazine-2-carboxylic acid. Part 7. Hydroperoxidation of higher alkanes". . p. 13051 - 13062. Retrieved 2007/10/03.