Lithium molybdate

Base Information

• Chemical Name: Lithium molybdate
• CAS No.: 13568-40-6
• Molecular Formula: Li2MoO4
• Molecular Weight: 173.82
• Hs Code.: 2841709000
• European Community (EC) Number: 236-977-7
• Wikipedia: Lithium molybdate,Lithium orthomolybdate,Lithium_molybdate
• Wikidata: Q2443527
• Mol file: 13568-40-6.mol

Synonyms:Lithium molybdate;13568-40-6;Dilithium molybdate;dilithium dioxido(dioxo)molybdenum;Molybdate (MoO42-), dilithium, (T-4)-;Lithium molybdate(VI);dilithium,dioxido(dioxo)molybdenum;MFCD00016178;Lithium Molybdate Powder;Li.1/2MoO4;Li.1/2Mo-O4;dilithium;dioxido(dioxo)molybdenum;EINECS 236-977-7;Molybdic acid (H2MoO4), dilithium salt;E79086;Molybdate (MoO42-), lithium (1:2), (T-4)-;Q2443527

Chemical Property of Lithium molybdate

Chemical Property:

• Appearance/Colour: white to almost white crystalline powder
• Melting Point: 705 °C
• PSA: 80.26000
• Density: 2.66 g/mL at 25 °C(lit.)
• LogP: -0.47520
• Sensitive.: Hygroscopic
• Water Solubility.: soluble
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 4
• Rotatable Bond Count: 0
• Exact Mass: 175.917069
• Heavy Atom Count: 7
• Complexity: 62.2

Purity/Quality:

98%,99%, ^*data from raw suppliers

Lithium molybdate, 99% ^*data from reagent suppliers

Safty Information:

• Pictogram(s): Xi
• Hazard Codes: Xi
• Statements: 36/37/38
• Safety Statements: 26-36/37/39-37/39

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

• Chemical Classes: Metals -> Metals, Inorganic Compounds
• Canonical SMILES: [Li+].[Li+].[O-][Mo](=O)(=O)[O-]
• Uses: Lithium molybdate can be used in comparative property studies of battery systems. Lithium molybdate is an additive for porcelain enamel coatings. Lithium molybdate can be used as an electrode material, a corrosion inhibitor, and a refrigerant. It has a three-dimensional framework that is useful in the fabrication of lithium-ion batteries. It facilitates the improvement of rate capability and cyclic stability of the electrochemical system.

Technology Process of Lithium molybdate

There total 20 articles about Lithium molybdate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 94.0%

molybdenum(VI) oxide + lithium hydroxide (1310-65-2) → lithium molybdate (13568-40-6)

Guidance literature:

In water; pH 7-7.5; 2 h boiling on water bath; filtering, drying;

Reference yield: 87.0%

molyddic acid + lithium hydroxide monohydrate (1310-66-3) → lithium molybdate (13568-40-6)

Guidance literature:

In water; H2MoO4*H2O (1 mmol) added to aq. soln. of LiOH*H2O (2 mmol), stirred for20 min; filtered, allowed to stant (air) at room temp. for 1 week;

DOI:10.1021/jp106028y

Reference yield:

lithium carbonate (554-13-2) + molybdenum(VI) oxide → lithium molybdate (13568-40-6)

Guidance literature:

MoO3:Li2CO3 (1:1); reaction begins at 300°C;

DOI:10.1103/PhysRev.117.416 DOI:10.1021/ac60203a013

upstream raw materials:

lithium carbonate

molybdenum

lithium hydroxide

lithium hydroxide monohydrate

Downstream raw materials:

molybdenum

Refernces

• 1、 Ryadun,Trifonov,Nadolinny,Pavlyuk,Rakhmanova. "Structure and properties of Li2–2xMg2+x(MoO4)3 crystals activated by copper ions". . p. 459 - 463. Retrieved 2016.
• 2、 Halperin, H.,Brauer, A. A.,Ben-Zvi, A.,Kristianpoller, N.. "". . p. 416 - 422. Retrieved 1960.
• 3、 Kozhevnikova,Kopylova. "Synthesis and electrical properties of ternary molybdates Li 3Ba2R3(MoO4)8 (R = La-Lu, Y)". . p. 384 - 387. Retrieved 2011.
• 4、 Kozhevnikova,Kopylova. "Synthesis and X-ray diffraction and IR spectroscopy studies of ternary molybdates Li3Ba2R3(MoO4) 8 (R = La-Lu, Y)". . p. 935 - 938. Retrieved 2011.
• 5、 Gudkova,Solodovnikova,Solodovnikov,Zolotova,Kurat'Eva. "Phase formation in Li2MoO4-K2MoO 4-MMoO4 (M = Ca, Pb, Ba) systems and the crystal structure of α-KLiMoO4". . p. 1443 - 1452. Retrieved 2011.
• 6、 Basovich,Khaikina. "Formation laws for scheelite-like triple molybdates LiMLn 2(MoO4)4". . p. 1082 - 1086. Retrieved 2006.
• 7、 Kim, Youhyuk,Lee, So-Ram. "X-ray Powder Diffraction Study of Molybdenum Oxides Formed From the Thermal Reactions of MoS2, MoS2/LiF, and MoS2/Ag in Air". . p. 1194 - 1199. Retrieved 2020.
• 8、 Zhou, Di,Randall, Clive A.,Wang, Hong,Pang, Li-Xia,Yao, Xi. "Microwave dielectric ceramics in Li2O-Bi2O 3-MoO3 system with ultra-low sintering temperatures". . p. 1096 - 1100. Retrieved 2010.
• 9、 Horowitz, H. H.,Metzger, G.. "". . p. 1464 - 1468. Retrieved 1963.
• 10、 Kozhevnikova,Kopylova. "Synthesis and study of Li3BaSrR3(MoO 4)8 compounds (R = La-Lu, Y) with stratified sheelite structure". . p. 1498 - 1501. Retrieved 2011.