Zirconium acetate

Base Information

• Chemical Name: Zirconium acetate
• CAS No.: 4229-34-9
• Molecular Formula: C2H4 O2 . 1/4 Zr
• Molecular Weight: 327.402
• European Community (EC) Number: 231-492-7,224-179-1
• DSSTox Substance ID: DTXSID20890586
• Nikkaji Number: J205.653D
• Wikidata: Q42414121
• Mol file: 4229-34-9.mol

Synonyms:ZIRCONIUM ACETATE;7585-20-8;zirconium(iv) acetate;Acetic acid, zirconium salt;zirconium(4+);tetraacetate;4229-34-9;Zirconium(4+) acetate;Acetic acid, zirconium(4+) salt;HSDB 2529;EINECS 224-179-1;EINECS 231-492-7;Acetic acid, zirconium salt (1:?);Acetic acid, zirconium(4+) salt (4:1);EC 231-492-7;C2H4O2.xZr;C2-H4-O2.x-Zr;Tetraacetoxyzirconium(IV);C2H4O2.1/4Zr;Acetic acid, zirconium(4) salt;DTXSID20890586;MFFVROSEPLMJAP-UHFFFAOYSA-J;C2-H4-O2.1/4Zr;Acetic acid, zirconium(4++) salt;MFCD00054410;AKOS028109701;A865608;Q42414121

Chemical Property of Zirconium acetate

Chemical Property:

• Boiling Point: 117.1°Cat760mmHg
• Flash Point: 40°C
• PSA: 40.13000
• Density: g/cm³
• LogP: -1.24380
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 8
• Rotatable Bond Count: 0
• Exact Mass: 325.957916
• Heavy Atom Count: 17
• Complexity: 25.5

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Chemical Classes: Metals -> Organic Acids, Metal Salts
• Canonical SMILES: CC(=O)[O-].CC(=O)[O-].CC(=O)[O-].CC(=O)[O-].[Zr+4]

Technology Process of Zirconium acetate

There total 7 articles about Zirconium acetate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 80.0%

zirconyl chloride octahydrate + acetic anhydride (108-24-7) + acetic acid (64-19-7,77671-22-8) → zirconium(IV) acetate (4229-34-9)

Guidance literature:

In acetic anhydride; acetic acid; byproducts: HCl; ZrOCl2*8H2O dissolved under reflux in MeCOOH and (MeCO)2O mixt. (1:9); cooled to room temp.; white deposit filtered; dried (vac., 50°C);elem. anal.;

DOI:10.1134/S0036023606110118

Reference yield:

zirconium(IV) chloride (10026-11-6) → zirconium(IV) acetate (4229-34-9)

Guidance literature:

With acetic anhydride; acetic acid; In tetrachloromethane; N2 atmosphere; refluxing (stirring, 5 h); pptn. on cooling, filtration off (N2 atmosphere), washing (Et2O), drying (vac.), recrystn. (acetic anhydride); elem. anal.;

DOI:10.1016/0584-8539(86)80039-3

Reference yield:

zirconium(IV) chloride (10026-11-6) + acetic acid (64-19-7,77671-22-8) → zirconium(IV) acetate (4229-34-9)

Guidance literature:

In acetic acid; byproducts: HCl; solution of ZrCl4 in boiling acetic acid;; pptn.;;

upstream raw materials:

acetic acid

zirconium(IV) chloride

acetic anhydride

zirconyl chloride

Downstream raw materials:

acetic acid

zirconium(IV) oxide

Refernces

• 1、 Kuz'mina,Altsybeev,Malkerova,Alikhanyan,Korsakov. "Zirconium pivalate: Synthesis and volatility". . p. 1750 - 1754. Retrieved 2006.