Bisphenol A divinyl ether

Base Information

• Chemical Name: Bisphenol A divinyl ether
• CAS No.: 3754-60-7
• Molecular Formula: C19H20 O2
• Molecular Weight: 280.367
• Hs Code.: 2909309090
• European Community (EC) Number: 223-160-5
• DSSTox Substance ID: DTXSID10884010
• Nikkaji Number: J217.652A
• Wikidata: Q82862771
• Mol file: 3754-60-7.mol

Synonyms:Bisphenol A divinyl ether;3754-60-7;Bisphenol A, divinyl ether;1,1'-Isopropylidenebis(4-(vinyloxy)benzene);1,1'-Isopropylidenebis[4-(vinyloxy)benzene];EINECS 223-160-5;Benzene, 1,1'-(1-methylethylidene)bis(4-(ethenyloxy)-;Benzene, 1,1'-(1-methylethylidene)bis[4-(ethenyloxy)-;SCHEMBL1023907;1-ethenoxy-4-[2-(4-ethenoxyphenyl)propan-2-yl]benzene;DTXSID10884010;METHYL(2-PROPENYLTHIO)ACETATE;2,2-bis-(4-vinyl-oxy-phenyl)propane;4,4'-(Propane-2,2-diyl)bis(vinyloxybenzene)

Chemical Property of Bisphenol A divinyl ether

Chemical Property:

• Boiling Point: 374.9°Cat760mmHg
• Flash Point: 134.5°C
• PSA: 18.46000
• Density: 1.023g/cm³
• LogP: 5.05710
• XLogP3: 5
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 2
• Rotatable Bond Count: 6
• Exact Mass: 280.146329876
• Heavy Atom Count: 21
• Complexity: 300

Purity/Quality:

99%, ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CC(C)(C1=CC=C(C=C1)OC=C)C2=CC=C(C=C2)OC=C

Technology Process of Bisphenol A divinyl ether

There total 3 articles about Bisphenol A divinyl ether which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 90.0%

BPA (80-05-7) + vinyl acetate (108-05-4,9003-20-7) → 1,1'-propane-2,2-diylbis[4-(vinyloxy)benzene] (3754-60-7)

Guidance literature:

With sodium acetate; bis(1,5-cyclooctadiene)diiridium(I) dichloride; In toluene; at 100 ℃; for 6h;

DOI:10.1021/ja0173932

Reference yield: 63.0%

BPA (80-05-7) + acetylene (74-86-2,25067-58-7) → 1,1'-propane-2,2-diylbis[4-(vinyloxy)benzene] (3754-60-7)

Guidance literature:

With potassium hydroxide semihydrate; In dimethyl sulfoxide; at 120 ℃; for 3h; under 9562.49 - 11769.2 Torr; Sealed tube;

DOI:10.1134/S1070428015020086

Reference yield:

→ 1,1'-propane-2,2-diylbis[4-(vinyloxy)benzene] (3754-60-7)

Guidance literature:

2.2-Bis-<4-hydroxy-phenyl>-propan, C2H2 in Dioxan, KOH;

upstream raw materials:

BPA

vinyl acetate

acetylene

Refernces

• 1、 Hirabayashi, Tomotaka,Sakaguchi, Satoshi,Ishii, Yasutaka,Davies, Paul W.,Fürstner, Alois. "Iridium-catalyzed synthesis of vinyl ethers from alcohols and vinyl acetate". . p. 55 - 58. Retrieved 2017/09/25.