(E,Z)-2,4-Decadienal

Base Information

• Chemical Name: (E,Z)-2,4-Decadienal
• CAS No.: 25152-83-4
• Molecular Formula: C10H16 O
• Molecular Weight: 152.236
• Hs Code.: 2912190090
• DSSTox Substance ID: DTXSID9058739
• Wikidata: Q81976923
• Metabolomics Workbench ID: 3541
• Mol file: 25152-83-4.mol

Synonyms:(E,Z)-2,4-Decadienal;(2E,4Z)-deca-2,4-dienal;25152-83-4;2E,4Z-Decadienal;trans-2,cis-4-Decadienal;2,4-Decadienal, (E,Z)-;2,4-Decadienal, (2E,4Z)-;2e,4e-decadienal;(E,E)-2,4-Decanedienal;(E,E)-deca-2,4-dienal;Deca-2(E),4(E)-dienal;(E)-2,(E)-4-decadienal;(2E,4Z)-Decadienal;(E,E)-2,4-Decadecenal;Deca-2(E),4(Z)-dienal;SCHEMBL1301734;DTXSID9058739;FEMA 3135;JZQKTMZYLHNFPL-NMMTYZSQSA-N;LMFA06000146

Chemical Property of (E,Z)-2,4-Decadienal

Chemical Property:

• Vapor Pressure: 0.03mmHg at 25°C
• Boiling Point: 244.6°Cat760mmHg
• Flash Point: 102.3°C
• PSA: 17.07000
• Density: 0.854g/cm³
• LogP: 2.87800
• XLogP3: 3.2
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 1
• Rotatable Bond Count: 6
• Exact Mass: 152.120115130
• Heavy Atom Count: 11
• Complexity: 134

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CCCCCC=CC=CC=O
• Isomeric SMILES: CCCCC/C=C\C=C\C=O

Technology Process of (E,Z)-2,4-Decadienal

There total 23 articles about (E,Z)-2,4-Decadienal which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 82.0%

(3E,5Z)-undeca-3,5-diene-1,2-diol (119239-12-2) → (2E,4Z)-2,4-decadienal (25152-83-4,65909-91-3)

Guidance literature:

With sodium periodate; In tetrahydrofuran; for 1h; Ambient temperature;

Reference yield: 81.0%

(2E,4Z)-5-iodopenta-2,4-dienal (168295-36-1) + (1-pentyl)zinc(II) bromide (308796-10-3) → (2E,4Z)-2,4-decadienal (25152-83-4,65909-91-3)

Guidance literature:

With cobalt acetylacetonate; lithium bromide; In tetrahydrofuran; 1-methyl-pyrrolidin-2-one; at -30 - 0 ℃; for 0.25h;

DOI:10.1016/S0040-4020(03)00382-X

Reference yield: 72.8%

(2E,4Z)-2,4-decadien-1-ol (16195-71-4) → (2E,4Z)-2,4-decadienal (25152-83-4,65909-91-3)

Guidance literature:

With manganese(IV) oxide; In hexane; for 1.5h; Ambient temperature;

DOI:10.1246/bcsj.63.1888

upstream raw materials:

3t-oxiranyl-propenal

hexyltriphenylphosphonium bromide

(2E,4Z)-2,4-decadien-1-ol

Dichloromethyl methyl ether

Downstream raw materials:

(3E,5Z)-1,3,5-undecatriene

(2E,4Z)-2,4-decadien-1-ol

1,7-dibromoheptane

9-hydroxy-(10E,12Z)-octadecadien-1-oic acid methyl ester

Refernces

• 1、 Ohloff,G.,Pawlak,M.. "-". . p. 1176 - 1179. Retrieved 1973.
• 2、 Akakabe, Yoshihiko,Matsui, Kenji,Kajiwara, Tadahiko. "2,4-Decadienals are produced via (R)-11-HPITE from arachidonic acid in marine green alga Ulva conglobata". . p. 3607 - 3609. Retrieved 2003.
• 3、 Vicart, Nicolas,Saboukoulou, Gerard-Simplice,Ramondenc, Yvan,Ple, Gerard. "Palladium catalyzed cross-coupling reaction of functional organozinc reagents with (2E,4E)- and (2E,4Z)-5-bromopenta-2,4-dienals: Easy access to functional conjugated dienic aldehydes". . p. 1509 - 1521. Retrieved 2007/10/03.