Azide ion

Base Information

• Chemical Name: Azide ion
• CAS No.: 14343-69-2
• Deprecated CAS: 15034-27-2
• Molecular Formula: N3
• Molecular Weight: 42.0201
• UNII: 88BIA49L8P
• DSSTox Substance ID: DTXSID8074310
• Nikkaji Number: J231.714A
• Wikidata: Q10853389
• ChEMBL ID: CHEMBL79455
• Mol file: 14343-69-2.mol

Synonyms:Azide;Azides

Chemical Property of Azide ion

Chemical Property:

• Melting Point: 119-120 °C (decomp)
• PSA: 12.36000
• LogP: -0.00830
• XLogP3: 1.5
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 2
• Rotatable Bond Count: 0
• Exact Mass: 42.009222013
• Heavy Atom Count: 3
• Complexity: 15.5

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Chemical Classes: Other Uses -> Explosives
• Canonical SMILES: [N-]=[N+]=[N-]

Technology Process of Azide ion

There total 26 articles about Azide ion which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 2.0%

triazidomercurate(II)(1-) → azide(1-) (14343-69-2,15034-27-2) + mercury

Guidance literature:

In ethanol; byproducts: nitrogen; Irradiation (UV/VIS); white or monochromated light (254 nm);

DOI:10.1016/S0277-5387(00)80448-9

Reference yield:

azidopentaamminecobalt(III) perchlorate + edtH2(2-) + hexacyanoferrate(II) → (ethylenediaminetetraacetato)cobalt(II)(2-) (110169-73-8,110169-72-7,14931-83-0) + azide(1-) (14343-69-2,15034-27-2) + perchlorate(1-) (14797-73-0,1059018-91-5) + hexacyanoferrate(III)

Guidance literature:

With sodium perchlorate; In water; byproducts: NH3; at 0.1 MPa and various temp. (290.2-308.2 K); Kinetics;

Reference yield:

nitrogen-15 (29817-79-6) + (14)-nitrogen (1173020-41-1) + ruthenium (7440-18-8) → NRu*(x)N2 + N(102)RuN + N(104)RuN + nitrogen(II) oxide (10102-43-9) + azide(1-) (14343-69-2,15034-27-2)

Guidance literature:

In solid matrix; other Radiation; the technique for laser (Nd:YAG) ablation; metal atoms were co-deposited with (14)N2 and (14)N2+(15)N2 in Ar (4%) at 5-8 mmol/h for 60-90 min and with undild. (14)N2 and (14)N2+(15)N2 for 30 min at the same rate; further products; isolated in solid Ar and N2 and identified by IR spectroscopy;

DOI:10.1021/jp993338s

upstream raw materials:

dinitrogen monoxide

azide radical

chlorite

nitrogen

Downstream raw materials:

nitrogen

lead(II) azide

hydrogen azide

Cu⁽²⁺⁾*N(CH₂CH₂OC₆H₄CH₂NHCH₂CH₂)3N*N₃^(1-)*OC₆H₂(NO₂)3^(1-)=[Cu(N(CH₂CH₂OC₆H₄CH₂NHCH₂CH₂)3N)(N₃)](OC₆H₂(NO₂)3)

Refernces

• 1、 Das, Tomi Nath,Huie, Robert E.,Neta. "Reduction potentials of so3·- , so5·- , and S4O6·3- radicals in aqueous solution". . p. 3581 - 3588. Retrieved 1999.
• 2、 Polak, Mark,Gruebele, Martin,Peng, Grace S.,Saykally, Richard J.. "Velocity modulation infrared laser spectroscopy of negative ions: The (011)- (001) band of azide (N3-)". . p. 110 - 114. Retrieved 1988.
• 3、 Shushakov, Anton A.,Pozdnyakov, Ivan P.,Grivin, Vjacheslav P.,Plyusnin, Victor F.,Vasilchenko, Danila B.,Zadesenets, Andrei V.,Melnikov, Alexei A.,Chekalin, Sergey V.,Glebov, Evgeni M.. "Primary photochemical processes for Pt(IV) diazido complexes prospectIVe in photodynamic therapy of tumors". . p. 9440 - 9450. Retrieved 2017/08/03.
• 4、 Ruiz,Juliarena,Wolcan,Ferraudi. "Kinetic and spectroscopic observations on the azidyl, N3{radical dot}, radical oxidation of fac-(Lspectator)ReI(CO)3(Lacceptor ) to fac-(Lspectator)ReII(CO)3(Laccepto r), Lspectator = 4,4′-bpy; Lacceptor ...". . p. 3681 - 3687. Retrieved 2008/10/09.