Dihydroxy(oxo)azanium;tetraethylazanium

Base Information

• Chemical Name: Dihydroxy(oxo)azanium;tetraethylazanium
• CAS No.: 1941-26-0
• Molecular Formula: C8H20N^.NO3
• Molecular Weight: 192.258
• Hs Code.: 29239000
• NSC Number: 152114
• Mol file: 1941-26-0.mol

Synonyms:dihydroxy(oxo)azanium;tetraethylazanium;Ethanaminium,N,N-triethyl-, nitrate;NSC152114;Tetraethylammonium nitrate, >=98.0% (NT)

Chemical Property of Dihydroxy(oxo)azanium;tetraethylazanium

Chemical Property:

• Appearance/Colour: white or off-white solid
• Melting Point: ~280 °C
• Refractive Index: 1.4450 (estimate)
• Boiling Point: >100 °C
• Flash Point: >100 °C
• PSA: 68.88000
• Density: 1.029 g/mL at 25 °C
• LogP: 2.16690
• Solubility.: acetonitrile: 0.1 g/mL, clear, colorless
• Hydrogen Bond Donor Count: 2
• Hydrogen Bond Acceptor Count: 3
• Rotatable Bond Count: 4
• Exact Mass: 194.16304257
• Heavy Atom Count: 13
• Complexity: 73.7

Purity/Quality:

98% ^*data from raw suppliers

Tetraethylammonium nitrate ^*data from reagent suppliers

Safty Information:

• Pictogram(s): Xi,O
• Hazard Codes: Xi,O
• Statements: 8-36/37/38
• Safety Statements: 26-36-17

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

• Canonical SMILES: CC[N+](CC)(CC)CC.[N+](=O)(O)O
• Uses: Tetraethylammonium nitrate can be used:To prepare nitronium triflate by reacting with triflic anhydride for subsequent use as a nitrating agent for benzene.To study the dependency of luminescence intensity of Eu3+?complexes on the nitrate anion concentration.To prepare the lanthanum(III) complex named (NEt4)[La(ntfa)4] by reacting with La(NO3)3·6H2O, NaOH and 4,4,4-trifluoro-1-(2-naphthyl)-1,3-butanedion.

Technology Process of Dihydroxy(oxo)azanium;tetraethylazanium

There total 7 articles about Dihydroxy(oxo)azanium;tetraethylazanium which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

ethyl iodide (75-03-6) + triethylamine (121-44-8) → tetraethylammonium iodide (68-05-3) + tetraethylammonium nitrate (1941-26-0)

Guidance literature:

With silver nitrate; In toluene; at 25 ℃; Concentration; Kinetics;

DOI:10.1016/j.molcata.2011.12.031

Reference yield:

tetraethylammonium bromide (71-91-0) → tetraethylammonium nitrate (1941-26-0)

Guidance literature:

With trimethyl phosphite; nitric acid; at 0 - 60 ℃; for 15h; Inert atmosphere; neat (no solvent);

DOI:10.1002/ejoc.201200370

Reference yield:

tetraethylammonium tetrakis(nitrato)borate → boron trioxide + tetraethylammonium nitrate (1941-26-0)

Guidance literature:

byproducts: NO2, O2; at 130°C;

DOI:10.1021/ja00953a051

upstream raw materials:

diethyl sulfate

triethylamine

tetraethyl-ammonium; chloride , compound with iodine trichloride

ethyl iodide

Downstream raw materials:

tetraethylammonium bis(1,3-diphenylpropane-1,3-dionato)nitratodioxouranate(VI)

Refernces

• 1、 Diop, Tidiane,Diop, Libasse,Michaud, Francois,Ardisson, Jose Domingos. "Et4N[NO3(SnClPh3)2(SnPh 3NO3)]: A trinuclear organostannate complex and related derivatives". . p. 83 - 88. Retrieved 2013.
• 2、 Vasilchenko, Danila,Topchiyan, Polina,Berdyugin, Semen,Filatov, Evgeny,Tkachev, Sergey,Baidina, Iraida,Komarov, Vladislav,Slavinskaya, Elena,Stadnichenko, Andrey,Gerasimov, Evgeny. "Tetraalkylammonium Salts of Platinum Nitrato Complexes: Isolation, Structure, and Relevance to the Preparation of PtOx/CeO2 Catalysts for Lowerature CO Oxidation". . p. 6075 - 6087. Retrieved 2019/04/25.