1,1,2-trimethylsiletane

Base Information

• Chemical Name: 1,1,2-trimethylsiletane
• CAS No.: 30681-90-4
• Molecular Formula: C6H14 Si
• Molecular Weight: 114.263
• Mol file: 30681-90-4.mol

Synonyms:1,1,2-Trimethyl-1-silacyclobutane;1,1,2-Trimethylsilacyclobutane

Chemical Property of 1,1,2-trimethylsiletane

Chemical Property:

• Vapor Pressure: 41.5mmHg at 25°C
• Boiling Point: 100.9°Cat760mmHg
• Flash Point: °C
• PSA: 0.00000
• Density: 0.78g/cm³
• LogP: 2.48860

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of 1,1,2-trimethylsiletane

There total 4 articles about 1,1,2-trimethylsiletane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

Chloro-(3-chloro-1-methyl-propyl)-dimethyl-silane → 1,1,2-Trimethyl-1-silacyclobutane (30681-90-4)

Guidance literature:

With magnesium;

DOI:10.1016/S0040-4020(01)96257-X

Reference yield:

methyl magnesium iodide (917-64-6) + 1,1-dichloro-2-methyl-1-silacyclobutane (30681-89-1) → 1,1,2-Trimethyl-1-silacyclobutane (30681-90-4)

Guidance literature:

In diethyl ether;

DOI:10.1016/S0022-328X(00)87837-7

Reference yield:

1,1-dimethylsilacyclobutane (2295-12-7) + Ketene (463-51-4) → 1,1-dimethyl-1-silacyclopentane (1072-54-4) + 1-methyl-1-ethyl-1-silacyclobutane (765-45-7) + 1,1,2-Trimethyl-1-silacyclobutane (30681-90-4) + 1,1,3-trimethyl-1-silacyclobutane (2295-13-8)

Guidance literature:

Irradiation;

DOI:10.1039/c39890000284

upstream raw materials:

methyl magnesium iodide

1,1-dichloro-2-methyl-1-silacyclobutane

1,1-dimethylsilacyclobutane

Ketene

Downstream raw materials:

iron pentacarbonyl

triiron dodecarbonyl

2,2,2,2-tetracarbonyl-1,1,5-trimethyl-1-sila-2-ferracyclopentane

1,1,5-trimethyl-2-phenyl-1-silacyclopentane

Refernces

• 1、 Cundy et al.. "-". . p. 99. Retrieved 1973.
• 2、 Frey, H. Monty,Walsh, Robin,Watts, Ivy M.. "The Insertion Reaction of 1CH2 into the Silicon-Carbon Bond". . p. 284 - 285. Retrieved 2007/10/02.