Cyclopentadienyl allyl palladiuM

Base Information

• Chemical Name: Cyclopentadienyl allyl palladiuM
• CAS No.: 1271-03-0
• Molecular Formula: C8H10 Pd
• Molecular Weight: 212.587
• Mol file: 1271-03-0.mol

Synonyms:Palladium,(h5-2,4-cyclopentadien-1-yl)(h3-2-propenyl)- (9CI); Palladium,allylcyclopentadienyl- (6CI); Palladium, p-allyl-p-cyclopentadienyl- (8CI); Palladium, p-allylcyclopentadienyl- (7CI); (h3-Allyl)(cyclopentadienyl)palladium;(h3-Allyl)(h5-cyclopentadienyl)palladium; (h5-h5-Cyclopentadienyl)(h3-cyclopropyl)palladium;Allyl(cyclopentadienyl)palladium; Allyl(h5-cyclopentadienyl)palladium; p-Allyl-p-cyclopentadienylpalladium; p-Cyclopentadienyl-p-allylpalladium

Chemical Property of Cyclopentadienyl allyl palladiuM

Chemical Property:

• Vapor Pressure: 418mmHg at 25°C
• Melting Point: 60-62 °C
• Boiling Point: 41.5°Cat760mmHg
• Flash Point: °C
• PSA: 0.00000
• Density: g/cm³
• LogP: 2.26300
• Sensitive.: air sensitive, store cold

Purity/Quality:

99%, ^*data from raw suppliers

Allyl(cyclopentadienyl)palladium ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Uses: Allyl(cyclopentadienyl)palladium(II) is used as: Volatile palladium catalyst with numerous uses in CVD and MOCVD applications. Starting material for the in situ generation of active palladium catalysts. An alternative to Pd(dba)2, a more reactive pre-catalyst for various catalytic reactions.

Technology Process of Cyclopentadienyl allyl palladiuM

There total 5 articles about Cyclopentadienyl allyl palladiuM which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 99.0%

bis(η3-allyl-μ-chloropalladium(II)) + sodium cyclopentadienylide (4984-82-1) → allyl(cyclopentadiene)palladium(II) (1271-03-0)

Guidance literature:

In tetrahydrofuran; benzene; at -20 - 20 ℃; for 1.5h; Inert atmosphere; Schlenk technique;

DOI:10.1002/anie.201508100

Reference yield: 95.0%

bis(η3-allyl-μ-chloropalladium(II)) + sodium cyclopentadienide → allyl(cyclopentadiene)palladium(II) (1271-03-0)

Guidance literature:

In tetrahydrofuran; at 20 ℃; for 0.5h; Inert atmosphere;

DOI:10.1039/c9cc02239b

Reference yield: 95.0%

bis[chloro(1,2,3-trihapto-allylbenzene)palladium(II)] + sodium cyclopentadienylide (4984-82-1) → allyl(cyclopentadiene)palladium(II) (1271-03-0)

Guidance literature:

In tetrahydrofuran; at -78 - 20 ℃; Inert atmosphere;

DOI:10.1021/jo400254q

upstream raw materials:

sodium cyclopentadienylide

Downstream raw materials:

[((R)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl)Pd(η3-benzyl)][CF3SO3]

[Pd(η3-naphthylmethyl)((R)-BINAP)](triflate)

palladium

ferrocene

Refernces

• 1、 Steinhoff, Patrick,Paul, Melanie,Schroers, Julian P.,Tauchert, Michael E.. "Highly efficient palladium-catalysed carbon dioxide hydrosilylation employing PMP ligands". . p. 1017 - 1022. Retrieved 2019.
• 2、 Thomas,Park. "Vapor phase deposition of palladium for electroless copper plating". . p. 1661 - 1666. Retrieved 1989.
• 3、 Pirkl, Nico,Del Grosso, Alessandro,Mallick, Bert,Doppiu, Angelino,Goo?en, Lukas J.. "Dihalogen-bridged NHC-palladium(i) dimers: Synthesis, characterisation and applications in cross-coupling reactions". supporting information. p. 5275 - 5278. Retrieved 2019/05/08.