Gold(1+) chloride

Base Information

• Chemical Name: Gold(1+) chloride
• CAS No.: 10294-29-8
• Molecular Formula: AuCl
• Molecular Weight: 232.419
• UNII: JD7Y972WU9
• Nikkaji Number: J95.927H
• Mol file: 10294-29-8.mol

Synonyms:gold(1+) chloride;GOLD MONOCHLORIDE [MI];CHEBI:30078;AKOS016009901

Chemical Property of Gold(1+) chloride

Chemical Property:

• Vapor Pressure: 33900mmHg at 25°C
• Melting Point: 289 °C (dec.)(lit.)
• PSA: 0.00000
• Density: 7.57 g/mL at 25 °C(lit.)
• LogP: -2.99850
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 1
• Rotatable Bond Count: 0
• Exact Mass: 231.935423
• Heavy Atom Count: 2
• Complexity: 0

Purity/Quality:

98%,99%, ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

• Canonical SMILES: [Cl-].[Au+]

Technology Process of Gold(1+) chloride

There total 24 articles about Gold(1+) chloride which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 83.0%

gold(III) chloride (21563-00-8) → gold(I) chloride (10294-29-8,11118-27-7)

Guidance literature:

With cyclohexene; In dichloromethane; N2-atmosphere; stirring (1 h, room temp.); collection (filtration), drying (vac.);

DOI:10.1039/DT9910003017

Reference yield: 60.0%

carbon disulfide (75-15-0,12122-00-8) + gold(III) chloride (21563-00-8) → AuCl2(η2-S2CCl) (125853-68-1) + gold(I) chloride (10294-29-8,11118-27-7)

Guidance literature:

In neat (no solvent); refluxing for 30 min; filtering, crystn. by concentration of soln., elem. anal.;

DOI:10.1039/c39890001495

Reference yield:

chlorine (7782-50-5) + gold (7440-57-5,457905-15-6) → gold(III) chloride (13453-07-1) + gold(I) chloride (10294-29-8,11118-27-7)

Guidance literature:

In neat (no solvent); powdery Au; at 180 to 190°C;; AuCl and small amounts of AuCl3 obtained;;

upstream raw materials:

gold

gold(III) chloride

chlorine

arsenite

Downstream raw materials:

chloro(2-methyl-5-phenyl-1,2,4,3σ(2)-triazaphosphole)gold(I)

N₃P₃(OC₆H₄(C₆H₅)2PAuCl)6

C₅₇H₇₈AuClN₆Ni₂O₂PS₂⁽¹⁺⁾*ClO₄^(1-)

gold(III) [18]tribenzo-pentaaza-triphyrin

Refernces

• 1、 Nalbandian,Boghosian,Papatheodorou. "Vaporization and vapor complexation in the gold(III) chloride-aluminum(III) chloride system". . p. 1769 - 1773. Retrieved 1992.
• 2、 Lenher, V.. "". . p. 546 - 552. Retrieved 1913.
• 3、 Diemer, M. E.. "". . p. 552 - 559. Retrieved 1913.
• 4、 Raeisaenen, Minna T.,Runeberg, Nino,Klinga, Martti,Nieger, Martin,Bolte, Michael,Pyykkoe, Pekka,Leskelae, Markku,Repo, Timo. "Coordination of pyridinethiols in gold(I) complexes". . p. 9954 - 9960. Retrieved 2007.
• 5、 Wu, Bin,Yang, Xiaojian,Yan, Mingdi. "Synthesis and Structure-Activity Relationship Study of Antimicrobial Auranofin against ESKAPE Pathogens". . p. 7751 - 7768. Retrieved 2019/09/10.
• 6、 -. "NON-CYANIDE GOLD COMPOUND". Paragraph 0017. . Retrieved 2017/02/28.