2,10-Epoxypinane

Base Information

• Chemical Name: 2,10-Epoxypinane
• CAS No.: 6931-54-0
• Molecular Formula: C10H16 O
• Molecular Weight: 152.236
• Hs Code.: 2910900090
• European Community (EC) Number: 230-055-8
• DSSTox Substance ID: DTXSID70863962
• Nikkaji Number: J195.376A
• Mol file: 6931-54-0.mol

Synonyms:2,10-Epoxypinane;beta-Pinene oxide;6931-54-0;beta-Pinene epoxide;Pinane, 2,10-epoxy-;6,6-dimethylspiro[bicyclo[3.1.1]heptane-2,2'-oxirane];CCRIS 3760;.beta.-Pinene oxide;EINECS 230-055-8;Spiro[bicyclo[3.1.1]heptane-2,2'-oxirane], 6,6-dimethyl-;BRN 0105830;Spiro(bicyclo(3.1.1)heptane-2,2'-oxirane), 6,6-dimethyl-;5-17-01-00423 (Beilstein Handbook Reference);2,10 - epoxypinane;ss-Pinenoxyd;beta pinene oxide;.beta.-Pinene epoxide;SCHEMBL260525;DTXSID70863962;AKOS006227869;LS-109793;EN300-1601456;A836426;Z1198147162;(1R,2R,5S)-6,6-dimethylspiro[norpinane-2,2'-oxirane]

Chemical Property of 2,10-Epoxypinane

Chemical Property:

• Appearance/Colour: clear colorless liquid
• Refractive Index: 1.476-1.481
• Boiling Point: 98-100 ºC (27 mmHg)
• Flash Point: 66 ºC
• PSA: 12.53000
• Density: 0.976
• LogP: 2.21150
• XLogP3: 2.1
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 1
• Rotatable Bond Count: 0
• Exact Mass: 152.120115130
• Heavy Atom Count: 11
• Complexity: 209

Purity/Quality:

99% ^*data from raw suppliers

(+)-BETA-PINENE OXIDE 95.00% ^*data from reagent suppliers

Safty Information:

• Hazard Codes: Xi
• Statements: 36/37/38
• Safety Statements: 37/39-26

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CC1(C2CCC3(C1C2)CO3)C

Technology Process of 2,10-Epoxypinane

There total 13 articles about 2,10-Epoxypinane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 91.0%

(1R,5R)-(+)-β-pinene (127-91-3,25719-60-2) → trans-2,10-epoxypinane (6931-54-0)

Guidance literature:

With dihydrogen peroxide; potassium hydrogencarbonate; dicyclohexyl-carbodiimide; In methanol; water; for 24h; Ambient temperature; other reagents: H₂O₂/Na₃PO₄*12H₂O/dicyclohexylcarbodiimide, H₂O₂/Amberlite IRC-50/dicyclohexylcarbodiimide, H₂O₂/KHCO₃/benzonitrile;

DOI:10.1021/jo972026n

Reference yield: 73.0%

Beta-pinene (177698-19-0,25719-60-2) → β-pinene oxide (6931-54-0)

Guidance literature:

With sodium percarbonate; N,N,N',N'-tetraacetylethylenediamine; sodium hydrogencarbonate; In dichloromethane;

DOI:10.21577/0103-5053.20190253

Reference yield:

→ C10H16O (875-08-1,6931-54-0,18680-30-3,23516-38-3,32162-29-1,56246-58-3)

Guidance literature:

8-Pinen, tert.-Amylhydroperoxid (TAHP);

DOI:10.1007/BF00923530

upstream raw materials:

beta-pinene

Beta-pinene

(1R,5R)-(+)-β-pinene

(+)-α-pinene

Downstream raw materials:

6,6-dimethylbicyclo<3.3.1>heptane-2-carboxaldehyde

myrtenol

(S)-(-)-perillyl pivalate

(R)-(+)-perillyl pivalate

Refernces

• 1、 Zheng, Weiguo,Hu, Haining,Chen, Yaju,Tan, Rong,Yin, Donghong. "Diamine-Decorated Graphene Oxide with Immobilized Gold Nanoparticles of Small Size for Alkenes Epoxidation with H2O2". . p. 3328 - 3337. Retrieved 2019.
• 2、 Wang, Chenlong,Zhan, Hongju,Lu, Xinhuan,Jing, Run,Zhang, Haifu,Yang, Lu,Li, Xixi,Yue, Fanfan,Zhou, Dan,Xia, Qinghua. "A recyclable cobalt(iii)-ammonia complex catalyst for catalytic epoxidation of olefins with air as the oxidant". . p. 2147 - 2156. Retrieved 2021/02/06.
• 3、 Benitez, Ricardo B.,Bermudez, John H.,Franco, Jaime M.,Rojas, Giovanni. "Easy Epoxidation of Monoterpenes from Common Starting Materials". . p. 1086 - 1092. Retrieved 2020/10/14.