DEUTERIUM CHLORIDE

Base Information

• Chemical Name: DEUTERIUM CHLORIDE
• CAS No.: 7698-05-7
• Molecular Formula: ClD
• Molecular Weight: 37.453
• Hs Code.: 28459000
• European Community (EC) Number: 231-715-8
• DSSTox Substance ID: DTXSID301043478
• Nikkaji Number: J95.232J
• Mol file: 7698-05-7.mol

Synonyms:Deuteriumchloride; Deuterium chloride (DCl); Deuterium monochloride; Hydrogen chloride(DCl); Hydrogen-d chloride

Chemical Property of DEUTERIUM CHLORIDE

Chemical Property:

• Vapor Pressure: 613 psi ( 21.1 °C)
• Melting Point: -114oC(lit.)
• Refractive Index: n20/D 1.355
• Boiling Point: °Cat760mmHg
• Flash Point: °C
• PSA: 0.00000
• Density: g/cm³
• LogP: 0.80200
• Sensitive.: Moisture Sensitive
• Water Solubility.: Fully miscible in water.
• XLogP3: 0.8
• Hydrogen Bond Donor Count: 1
• Hydrogen Bond Acceptor Count: 0
• Rotatable Bond Count: 0
• Exact Mass: 36.9829545
• Heavy Atom Count: 1
• Complexity: 0

Purity/Quality:

98%,99%, ^*data from raw suppliers

Deuterium Chloride 35% in D2O ^*data from reagent suppliers

Safty Information:

• Pictogram(s): Xi
• Hazard Codes: T,C,Xn,F,Xi,F+
• Statements: 34-37-68-66-36/37/38-19-11-23-23/25-12-67-22-35
• Safety Statements: 26-36/37/39-45-46-36/37-16-23-9

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

• Chemical Classes: Toxic Gases & Vapors -> Acids, Inorganic
• Canonical SMILES: Cl
• Isomeric SMILES: [2H]Cl
• Uses: Deuterium chloride solution has been used to study:The kinetics of chitosan reacetylation using acetic anhydride and acetic acid.Regioselective terminal group activation of chitosan by thioacetylation.The complex formation between cyclodextrin and captopril in aqueous solution using NMR spectroscopy.

Technology Process of DEUTERIUM CHLORIDE

There total 47 articles about DEUTERIUM CHLORIDE which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 75.0%

hydrogenchloride (7647-01-0,15364-23-5) + sulfuric acid-d2 (13813-19-9) → hydrogen chloride (7698-05-7)

Guidance literature:

In further solvent(s); HCl/Kr gaseous mixt/ passed through tube with (2)H2SO4 droplets at temp.down 8 K;

DOI:10.1063/1.1560635

Reference yield:

nitrogen + chloroform-d1 (865-49-6) → clorine (14700-96-0,14835-24-6,15723-23-6,16547-50-5,16885-04-4,16887-00-6,16904-11-3,16904-12-4,16999-02-3,20337-89-7,20499-73-4,22537-15-1,22537-27-5,22541-73-7,22541-74-8,24203-47-2,33944-49-9,34937-26-3,37352-90-2) + hydrogen chloride (7698-05-7) + cyanogen chloride (506-77-4)

Guidance literature:

very low pressure reactor (VLPR) technique; not isolated; monitored by mass spectrometry; Kinetics;

DOI:10.1021/j100172a035

Reference yield:

pentadeuterioethyl (71668-46-7) + clorine (14700-96-0,14835-24-6,15723-23-6,16547-50-5,16885-04-4,16887-00-6,16904-11-3,16904-12-4,16999-02-3,20337-89-7,20499-73-4,22537-15-1,22537-27-5,22541-73-7,22541-74-8,24203-47-2,33944-49-9,34937-26-3,37352-90-2) → Ethylene-d4 (683-73-8,25549-98-8) + hydrogen chloride (7698-05-7)

Guidance literature:

React. (295 K total pressure less than 5 mTorr) with very low pressure reactor technique (VLPR).; Kinetics;

DOI:10.1021/ja00183a010

upstream raw materials:

clorine

chloroform-d1

deuterium

ethane-d6

Downstream raw materials:

cis-dichlorobis(triphenylphosphine)platinum(II)

clorine

water

deuterium sulfide

Refernces

• 1、 Gola, Agnieszka A.,Sarzyński, Dariusz,Dry?, Andrzej,Jodkowski, Jerzy T.. "Kinetic study of the reaction of chlorine atoms with chloroform in the gas phase". . p. 250 - 254. Retrieved 2009.
• 2、 Lewis, G. N.,MacDonald, R. T.,Schutz, P. W.. "". . p. 494 - 495. Retrieved 1934.
• 3、 Rakitzis, T. Peter,Kandel, S. Alex,Lev-On, Topaz,Zare, Richard N.. "Differential cross section polarization moments: Location of the D-atom transfer in the transition-state region for the reactions CI+C2D6→DCI(v′= 0, J′=1)+C2D5 and CI+CD4→DCI(v′=0,J′=1)+CD3". . p. 9392 - 9405. Retrieved 1997.
• 4、 Husain, David,Plane, John M. C.,Xiang, Chen Cong. "". . . Retrieved 1984.
• 5、 Krim,Alikhani. "Infrared spectra and theoretical calculations of HCl complexed with NO". . p. 265 - 271. Retrieved 1998.
• 6、 Yu, Wenjie,Andrews, Lester,Wang, Xuefeng. "Infrared Spectroscopic and Electronic Structure Investigations of Beryllium Halide Molecules, Cations, and Anions in Noble Gas Matrices". . p. 8843 - 8855. Retrieved 2017.
• 7、 Li, Lin,Stüker, Tony,Andrews, Lester,Beckers, Helmut,Riedel, Sebastian. "Infrared Spectra of the HAnX and H2AnX2 Molecules (An=Th and U, X=Cl and Br) in Argon Matrices Supported by Electronic Structure Calculations". . p. 1795 - 1805. Retrieved 2019.
• 8、 Di Sarra, Francesca,Fresch, Barbara,Bini, Riccardo,Saielli, Giacomo,Bagno, Alessandro. "Reactivity of auranofin with selenols and thiols - Implications for the anticancer activity of gold(I) compounds". . p. 2718 - 2727. Retrieved 2013/07/11.