Bis(2-oxoethyl)mercury

Base Information

• Chemical Name: Bis(2-oxoethyl)mercury
• CAS No.: 4387-13-7
• Molecular Formula: C4H6HgO2
• Molecular Weight: 286.68
• Hs Code.: 2931900090
• DSSTox Substance ID: DTXSID60195966
• Mol file: 4387-13-7.mol

Synonyms:Bis(2-oxoethyl)mercury;Mercuridiacetaldehyde;Bis(formylmethyl)mercury;Mercury, bis(2-oxoethyl)-;BRN 3660631;4387-13-7;Acetaldehyde, mercuridi- (6CI,7CI);MERCURY, BIS(FORMYLMETHYL)-;4-04-00-04434 (Beilstein Handbook Reference);Acetaldehyde, mercuridi-;C4H6HgO2;C4-H6-Hg-O2;SCHEMBL3806980;DTXSID60195966;LS-89653

Chemical Property of Bis(2-oxoethyl)mercury

Chemical Property:

• Melting Point: 93°C
• Boiling Point: °Cat760mmHg
• Flash Point: °C
• PSA: 0.00000
• Density: g/cm³
• LogP: 1.11830
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 2
• Rotatable Bond Count: 2
• Exact Mass: 288.007423
• Heavy Atom Count: 7
• Complexity: 54.7

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C(C=O)[Hg]CC=O

Technology Process of Bis(2-oxoethyl)mercury

There total 6 articles about Bis(2-oxoethyl)mercury which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

HOCH2C6H4CH(O)(C6H2)(C6H3)OCl2(OCHCH2) + mercury dichloride → bis(formylmethyl)mercury (4387-13-7)

Guidance literature:

With PSB buffer; In water; dimethyl sulfoxide; ligand in PSB buffer (pH 7.4) with 5% DMSO added to aq. soln. of HgCl2; SPE;

DOI:10.1039/b900380k

Reference yield:

-butyl vinyl ether (111-34-2,92680-80-3) + mercury(II) diacetate (1600-27-7) → bis(formylmethyl)mercury (4387-13-7)

Guidance literature:

With methanol; mercury(II) oxide; und Behandeln des Reaktionsprodukts mit wss.H₂SO₄;

Reference yield:

ethyl vinyl ether (109-92-2,25104-37-4) → bis(formylmethyl)mercury (4387-13-7)

Guidance literature:

und Behandeln des Reaktionsprodukts mit wss.HCl;

upstream raw materials:

-butyl vinyl ether

mercury(II) diacetate

ethanol

ethyl vinyl ether

Downstream raw materials:

Dibutyl-vinyl-phosphit

phosphorous acid diphenyl ester-vinyl ester

phenyl-tris-vinyloxy-silane

vinyl pivalate

Refernces