BIANTHRONYL

Base Information

• Chemical Name: BIANTHRONYL
• CAS No.: 434-84-4
• Molecular Formula: C28H18 O2
• Molecular Weight: 386.45
• Hs Code.: 2914690090
• European Community (EC) Number: 635-142-8
• NSC Number: 102943,627653
• UNII: PBH43F9Y7H
• DSSTox Substance ID: DTXSID80195842
• Nikkaji Number: J79.617D
• Wikidata: Q83068897
• Mol file: 434-84-4.mol

Synonyms:10,10'-Bianthrone(7CI); 10,10'-Bianthronyl; 10,10'-Dianthronyl; Bianthronyl; Dianthrone; NSC102943; NSC 627653

Chemical Property of BIANTHRONYL

Chemical Property:

• Vapor Pressure: 3.66E-10mmHg at 25°C
• Melting Point: 272°C(dec.)(lit.)
• Boiling Point: 500.9°Cat760mmHg
• Flash Point: 185.2°C
• PSA: 34.14000
• Density: 1.293g/cm³
• LogP: 5.73940
• XLogP3: 6.1
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 2
• Rotatable Bond Count: 1
• Exact Mass: 386.130679813
• Heavy Atom Count: 30
• Complexity: 572

Purity/Quality:

98%,99%, ^*data from raw suppliers

Bianthronyl >97.0%(HPLC) ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

• Canonical SMILES: C1=CC=C2C(=C1)C(C3=CC=CC=C3C2=O)C4C5=CC=CC=C5C(=O)C6=CC=CC=C46

Technology Process of BIANTHRONYL

There total 38 articles about BIANTHRONYL which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 80.0%

9,10-phenanthrenequinone (84-65-1) → 2-hydroxy-9,10-anthraquinone (605-32-3) + anthracen-9(10H)-one (90-44-8) + 1-hydroxyanthraquinone (129-43-1) + bianthronyl (434-84-4)

Guidance literature:

In sulfuric acid; at 15 ℃; Product distribution; Mechanism; Quantum yield; Irradiation; N₂;

DOI:10.1039/c39800000676

Reference yield: 55.0%

anthracene (120-12-7) → bianthronyl (434-84-4) + 9,10-phenanthrenequinone (84-65-1)

Guidance literature:

With Oxone; In water; acetonitrile; for 36h; Reflux;

DOI:10.1016/j.tet.2012.09.028

Reference yield: 50.0%

anthracen-9(10H)-one (90-44-8) → bianthronyl (434-84-4) + 9,10-phenanthrenequinone (84-65-1)

Guidance literature:

With *5H2O; lithium chloride; In acetic acid; at 100 ℃; for 4h;

DOI:10.1246/bcsj.62.3567

upstream raw materials:

diethyl ether

10-bromo-10H-anthracen-9-one

9-anthrol

anthracene

Downstream raw materials:

phenanthro[1,10,9,8-opra]prylene-7,14-dione

bianthrone

9,10-phenanthrenequinone

anthracen-9(10H)-one

Refernces

• 1、 Hamanoue, Kumao,Nakayama, Toshihiro,Kajiwara, Kanji,Yamanaka, Shigenobu,Ushida, Kiminori. "Photophysics and Photochemistry of Nitroanthracenes. Part 2. Primary Process in the Photochemical Reaction of 9-Nitroanthracene studied by Steady-state Photolysis and Laser Photolysis". . p. 3145 - 3152. Retrieved 1992.
• 2、 Parida, Keshaba Nanda,Jhulki, Samik,Mandal, Susovan,Moorthy, Jarugu Narasimha. "Oxidation of benzyl alcohols, benzyl halides, and alkylbenzenes with oxone". . p. 9763 - 9768,6. Retrieved 2020/08/20.
• 3、 Pesti,Huhn,Yin,Xing,Fortunak,Earl. "Efficient pyridinylmethyl functionalization: Synthesis of 10,10-bis[(2-fluoro-4-pyridinyl)methyl]-9(10H)-anthracenone (DMP 543), an acetylcholine release enhancing agent". . p. 7718 - 7722. Retrieved 2007/10/03.