Diethyl peroxide

Base Information

• Chemical Name: Diethyl peroxide
• CAS No.: 628-37-5
• Molecular Formula: C4H10 O2
• Molecular Weight: 90.1222
• European Community (EC) Number: 211-041-0
• UN Number: 9183
• UNII: Q327D55J19
• DSSTox Substance ID: DTXSID8073922
• Nikkaji Number: J6.877B
• Wikidata: Q15726032
• Metabolomics Workbench ID: 55241
• Mol file: 628-37-5.mol

Synonyms:Diethyl peroxide;Ethyl peroxide;PEROXIDE, DIETHYL;628-37-5;(ethylperoxy)ethane;1,1'-dioxydiethane;1-(Ethylperoxy)ethane;UNII-Q327D55J19;EINECS 211-041-0;Q327D55J19;1-(Ethylperoxy)ethane #;DTXSID8073922;CHEBI:35929;Q15726032

Chemical Property of Diethyl peroxide

Chemical Property:

• Vapor Pressure: 173mmHg at 25°C
• Melting Point: -70 C
• Refractive Index: 1.3715
• Boiling Point: 65 C (this has not been checked - one might expect this material todecompose rather than boil)
• Flash Point: 4.7°C
• Density: 0.839g/cm³
• XLogP3: 0.9
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 2
• Rotatable Bond Count: 3
• Exact Mass: 90.068079557
• Heavy Atom Count: 6
• Complexity: 17.5

Purity/Quality:

99%, ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CCOOCC

Technology Process of Diethyl peroxide

There total 8 articles about Diethyl peroxide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 61.0%

diethyl sulfate (64-67-5) → diethyl peroxide (628-37-5)

Guidance literature:

With potassium hydroxide; dihydrogen peroxide; In water; 1.) 20-25 deg C, 3 h; 2.) RT, overnight;

DOI:10.1021/ja00304a030

Reference yield:

triethylbismuth (617-77-6) → diethyl ether (60-29-7,927820-24-4) + ethanol (64-17-5) + ethene (74-85-1) + diethyl peroxide (628-37-5)

Guidance literature:

at -40 - 25 ℃; und andere Produkte: Aethoxy-diaethyl-bismutin, Bi₂O₃;

DOI:10.1021/ja01254a046

Reference yield:

triethylbismuth (617-77-6) → C0.28H0.63BiO2.5 + diethyl ether (60-29-7,927820-24-4) + diethyl peroxide (628-37-5)

Guidance literature:

byproducts: ethanol;

DOI:10.1039/J39710001660

upstream raw materials:

diethyl sulfate

azoethane

diethyl sulphide

triethylbismuth

Downstream raw materials:

biphenyl

Phenetole

ethanol

dimethylglyoxal

Refernces

• 1、 Nangia,Benson. "". . p. 1882. Retrieved 1962.
• 2、 Niki, H.,Maker, P. D.,Savage, C. M.,Breitenbach, L. P.. "Fourier Transform Infrared Studies of the Self-Reaction of C2H5O2 Radicals". . p. 3825 - 3829. Retrieved 2007/10/02.