Dichlorofluoromethanesulfenyl chloride

Base Information

• Chemical Name: Dichlorofluoromethanesulfenyl chloride
• CAS No.: 2712-93-8
• Molecular Formula: CCl3FS
• Molecular Weight: 169.434
• European Community (EC) Number: 220-310-1
• DSSTox Substance ID: DTXSID00181585
• Nikkaji Number: J80.547E
• Wikidata: Q83052208
• Mol file: 2712-93-8.mol

Synonyms:Dichlorofluoromethanesulfenyl chloride;2712-93-8;Dichlorofluoromethanesulphenyl chloride;Methanesulfenyl chloride, dichlorofluoro-;EINECS 220-310-1;Fluorodichloromethane sulfenylchloride;BRN 0906741;Cl2FCSCl;CCl3FS;C-Cl3-F-S;SCHEMBL2839991;DTXSID00181585;MFCD01715484;fluorodichloromethanesulphenyl chloride;AKOS006279303;dichlorofluoromethane sulphenyl chloride;fluorodichloromethane-sulphenyl chloride;LS-90054;W-109135

Chemical Property of Dichlorofluoromethanesulfenyl chloride

Chemical Property:

• Vapor Pressure: 31.5mmHg at 25°C
• Refractive Index: 1.506
• Boiling Point: 107.5 °C at 760 mmHg
• Flash Point: 18.8 °C
• PSA: 25.30000
• Density: 1.717 g/cm³
• LogP: 2.93180
• XLogP3: 3
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 2
• Rotatable Bond Count: 0
• Exact Mass: 167.877032
• Heavy Atom Count: 6
• Complexity: 46.1

Purity/Quality:

99.0% ^*data from raw suppliers

Dichlorofluoromethanesulfenylchloride ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C(F)(SCl)(Cl)Cl

Technology Process of Dichlorofluoromethanesulfenyl chloride

There total 23 articles about Dichlorofluoromethanesulfenyl chloride which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 66.4%

chlorothio-trichloro-methane (594-42-3) → dichlorofluoromethanesulphenyl chloride (2712-93-8)

Guidance literature:

With iron(III) trifluoride; 18-crown-6 ether; pyridine hydrogenfluoride; In toluene; at 103 - 108 ℃; Temperature;

Reference yield: 63.0%

(CH3)2CH(CFCl2S)NC(Cl)NSCFCl2 → (CH3)2CH(CFCl2S)NCN (51093-51-7) + dichlorofluoromethanesulphenyl chloride (2712-93-8)

Guidance literature:

Reference yield:

3-<(Dichlorfluormethyl)sulfinyl>-1-propen (107729-28-2) → 4,4-Dichlor-4-fluor-1-buten (590-39-6) + 1,5-Hexadien (592-42-7) + 1-Chlor-1-fluor-1,3-butadien (407-08-9) + CFC-112a (76-12-0) + dichlorofluoromethanesulphenyl chloride (2712-93-8)

Guidance literature:

at 400 ℃; for 1h; under 0.01 - 1 Torr; Product distribution;

upstream raw materials:

N-[(trichloromethyl)sulfanyl]diethylamine

chlorothio-trichloro-methane

bis(dichlorofluoromethyl)disulfane

chlorocarbonyl isocyanate

Downstream raw materials:

(+/-)-(trans-2-chloro-cyclohexyl)-(dichloro-fluoro-methyl)-sulfide

benzyl dichloro-fluoromethyl sulfide

Dichlorfluormethyl-2-chlorcyclohexyl-sulfid

Dichlorfluormethyl-cyclohexylsulfid

Refernces

• 1、 Moule,Subramaniam. "". . p. 943. Retrieved 1970.
• 2、 Ham. "". . p. 751. Retrieved 1961.
• 3、 -. "N, N-dimethyl-N-phenyl-(N- fluorine two chlorine armor thio)-sulfonaide synthesis process". Paragraph 0079-0082; 0084; 0087; 0088. . Retrieved 2017/02/09.
• 4、 Holoch, Jan,Sundermeyer, Wolfgang. "Methyl-halogenated Allyl Methyl Sulfoxides and Sulfones and the Synthesis of Halogenated Sulfines". . p. 269 - 278. Retrieved 2007/10/02.