tetradecane-1,14-diamine

Base Information

• Chemical Name: tetradecane-1,14-diamine
• CAS No.: 7735-02-6
• Molecular Formula: C14H32N2
• Molecular Weight: 228.421
• Mol file: 7735-02-6.mol

Synonyms:1,14-Diaminotetradecane;Myristyldiamine;

Chemical Property of tetradecane-1,14-diamine

Chemical Property:

• Vapor Pressure: 0.000815mmHg at 25°C
• Refractive Index: 1.466
• Boiling Point: 305.6 °C at 760 mmHg
• Flash Point: 181.5 °C
• Density: 0.855 g/cm³

Purity/Quality:

99%, ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of tetradecane-1,14-diamine

There total 7 articles about tetradecane-1,14-diamine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 82.0%

1,14-tetradecanediol (19812-64-7) → α,ω-diaminotetradecane (7735-02-6)

Guidance literature:

With carbonylchlorohydrido(4,5-bis((diisopropylphosphino)methyl)acridine)ruthenium(II); ammonia; In toluene; at 150 ℃; for 65h; Autoclave; Inert atmosphere;

DOI:10.1002/cctc.201800365

Reference yield:

7-chloroheptanoic acid (821-57-8) → α,ω-diaminotetradecane (7735-02-6)

Guidance literature:

Multi-step reaction with 3 steps

1: Na / methanol / (electrolysis)

2: dimethylformamide

3: H₂, NH₃ / Raney-Ni / methanol

With ammonia; hydrogen; sodium; nickel; In methanol; N,N-dimethyl-formamide;

DOI:10.1246/bcsj.39.480

Reference yield:

Tetradecandisaeuredinitril (7735-44-6) → α,ω-diaminotetradecane (7735-02-6)

Guidance literature:

With ammonia; hydrogen; nickel; In methanol;

DOI:10.1246/bcsj.39.480

upstream raw materials:

Tetradecandisaeuredinitril

1,12-dichlorododecane

7-chloroheptanoic acid

1,14-tetradecanediol

Refernces

• 1、 Sung, Sihyong,Jeon, Hyunwoo,Sarak, Sharad,Ahsan, Md Murshidul,Patil, Mahesh D.,Kroutil, Wolfgang,Kim, Byung-Gee,Yun, Hyungdon. "Parallel anti-sense two-step cascade for alcohol amination leading to ω-amino fatty acids and α,ω-diamines". supporting information. p. 4591 - 4595. Retrieved 2018/10/23.