2,2,3,3,4,4,5,5,6,6,7,7-Dodecafluoroheptyl acrylate

Base Information

• Chemical Name: 2,2,3,3,4,4,5,5,6,6,7,7-Dodecafluoroheptyl acrylate
• CAS No.: 2993-85-3
• Molecular Formula: C10H6F12O2
• Molecular Weight: 386.137
• Hs Code.: 29161290
• European Community (EC) Number: 221-064-8
• DSSTox Substance ID: DTXSID80184039
• Nikkaji Number: J205.286E
• Wikidata: Q81985499
• Mol file: 2993-85-3.mol

Synonyms:2993-85-3;1H,1H,7H-Dodecafluoroheptyl acrylate;2,2,3,3,4,4,5,5,6,6,7,7-Dodecafluoroheptyl acrylate;2-Propenoic acid, 2,2,3,3,4,4,5,5,6,6,7,7-dodecafluoroheptyl ester;(6H-Perfluorohexyl)methyl acrylate;1h,1h,7h-perfluoroheptyl acrylate;EINECS 221-064-8;2,2,3,3,4,4,5,5,6,6,7,7-dodecafluoroheptyl prop-2-enoate;1H,1H,7H-DODECAFLUOROHEPTYLACRYLATE;2,2,3,3,4,4,5,5,6,6,7,7-Dodecafluoroheptyl Acrylate (stabilized with TBC);DFHA;SCHEMBL710565;DTXSID80184039;C10H6F12O2;MFCD00080746;AKOS015912631;C10-H6-F12-O2;FS-4161;LS-185637;D4989;FT-0607840;Acrylic acid 1H,1H,7H-dodecafluoroheptyl ester;D90356;J-017702;2,2,3,3,4,4,5,5,6,6,7,7-Dodecafluoroheptyl acrylate, 95%;acrylic acid 2,2,3,3,4,4,5,5,6,6,7,7-dodecafluoro-heptyl ester;Acrylic Acid 2,2,3,3,4,4,5,5,6,6,7,7-Dodecafluoroheptyl Ester

Chemical Property of 2,2,3,3,4,4,5,5,6,6,7,7-Dodecafluoroheptyl acrylate

Chemical Property:

• Vapor Pressure: 0.279mmHg at 25°C
• Refractive Index: n20/D 1.342(lit.)
• Boiling Point: 203.4 °C at 760 mmHg
• Flash Point: 74.9 °C
• PSA: 26.30000
• Density: 1.495 g/cm³
• LogP: 4.15720
• Storage Temp.: Keep Cold
• XLogP3: 4.9
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 14
• Rotatable Bond Count: 9
• Exact Mass: 386.0176174
• Heavy Atom Count: 24
• Complexity: 484

Purity/Quality:

98%,99%, ^*data from raw suppliers

2,2,3,3,4,4,5,5,6,6,7,7-Dodecafluoroheptyl Acrylate (stabilized with TBC) >97.0%(GC) ^*data from reagent suppliers

Safty Information:

• Pictogram(s): Xi
• Hazard Codes: Xi
• Statements: 36/37/38
• Safety Statements: 26-36

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

• Canonical SMILES: C=CC(=O)OCC(C(C(C(C(C(F)F)(F)F)(F)F)(F)F)(F)F)(F)F
• Uses: 1H,1H,7H-Dodecafluoroheptyl Acrylate (CAS# 2993-85-3) is a polymerizable liquid crystal that can be used as an optically anisotropic film, optical film, polarizing plate, and image display device. It can also be used to produce particulate vinyliden-fluoride-based polymer.

Technology Process of 2,2,3,3,4,4,5,5,6,6,7,7-Dodecafluoroheptyl acrylate

There total 4 articles about 2,2,3,3,4,4,5,5,6,6,7,7-Dodecafluoroheptyl acrylate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 98.5%

2,2,3,3,4,4,5,5,6,6,7,7-dodecafluoro-1-heptanol (335-99-9) + acrylic acid methyl ester (292638-85-8,9003-21-8,96-33-3) → 2,2,3,3,4,4,5,5,6,6,7,7-dodecafluoroheptyl acrylate (2993-85-3)

Guidance literature:

With tetrakis(1H,1H,7H-perfluoroheptyl) titanate; hydroquinone; In toluene; at 80 ℃; for 3h; Reagent/catalyst; Large scale;

Reference yield: 76.1%

potassium acrylate (10192-85-5) + 2,2,3,3,4,4,5,5,6,6,7,7-Dodecafluoroheptyl chlorosulfite (254756-56-4) → 2,2,3,3,4,4,5,5,6,6,7,7-dodecafluoroheptyl acrylate (2993-85-3)

Guidance literature:

DOI:10.1023/A:1020788902312

Reference yield: 45.2%

2,2,3,3,4,4,5,5,6,6,7,7-dodecafluoro-1-heptanol (335-99-9) + acrylic acid (79-10-7) → 2,2,3,3,4,4,5,5,6,6,7,7-dodecafluoroheptyl acrylate (2993-85-3)

Guidance literature:

With hydroquinone; sulfonated coal; sulfuric acid; In toluene; at 100 ℃;

upstream raw materials:

2,2,3,3,4,4,5,5,6,6,7,7-dodecafluoro-1-heptanol

acrylic acid

potassium acrylate

2,2,3,3,4,4,5,5,6,6,7,7-Dodecafluoroheptyl chlorosulfite

Refernces

• 1、 Igumnov, S. M.,Sokolov, V. I.,Men'Shikov, V. K.,Mel'Nik, O. A.,Boiko, V. E.,Dyachenko, V. I.,Nikitin, L. N.,Khaidukov, E. V.,Yurkov, G. Yu.,Buznik, V. M.. "Fluorinated monomers and polymers with specific properties for integrated optics and photonics". . p. 183 - 187,5. Retrieved 2020/09/16.
• 2、 Gol'din,Averbakh,Nekrasova,Lavygin,Leitan,Chalbysheva. "SYNTHESIS AND PHYSICOCHEMICAL PROPERTIES OF ORGANOFLUORINE ESTERS OF ACRYLIC, METHACRYLIC, AND MALEIC ACIDS.". . p. 1244 - 1247. Retrieved 2007/10/02.