4-Methylphenanthrene

Base Information

• Chemical Name: 4-Methylphenanthrene
• CAS No.: 832-64-4
• Molecular Formula: C15H12
• Molecular Weight: 192.26
• European Community (EC) Number: 212-621-6
• NSC Number: 21046
• UNII: 4931P56DVP
• DSSTox Substance ID: DTXSID7073933
• Nikkaji Number: J143.942A
• Wikidata: Q27259217
• Mol file: 832-64-4.mol

Synonyms:4-METHYLPHENANTHRENE;832-64-4;Phenanthrene, 4-methyl-;METHYLPHENANTHRENE;Phenanthrene, methyl-;UNII-4931P56DVP;4931P56DVP;EINECS 212-621-6;NSC 21046;NSC-21046;31711-53-2;NSC21046;4-methyl-phenanthrene;DTXSID7073933;AKOS024329379;FT-0692553;Q27259217

Chemical Property of 4-Methylphenanthrene

Chemical Property:

• Vapor Pressure: 7.27E-05mmHg at 25°C
• Melting Point: 53.5°C
• Refractive Index: 1.6031 (estimate)
• Boiling Point: 353.5°C at 760 mmHg
• Flash Point: 157.5°C
• PSA: 0.00000
• Density: 1.105g/cm³
• LogP: 4.30140
• XLogP3: 5.1
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 0
• Rotatable Bond Count: 0
• Exact Mass: 192.093900383
• Heavy Atom Count: 15
• Complexity: 220

Purity/Quality:

99% ^*data from raw suppliers

4-Methylphenanthrene ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CC1=C2C(=CC=C1)C=CC3=CC=CC=C32
• Uses: 4-Methylphenanthrene is a derivative of phenanthrene (P294800) which is a polycyclic aromatic hydrocarbons, an environmental pollutant.

Technology Process of 4-Methylphenanthrene

There total 51 articles about 4-Methylphenanthrene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 95.0%

(2'-methylbiphenyl-2-yl)acetaldehyde → 4-methylphenanthrene (832-64-4)

Guidance literature:

With trifluorormethanesulfonic acid; at 0 ℃; for 0.333333h;

DOI:10.1002/ejoc.201601406

Reference yield: 88.0%

2-ethynyl-2'-methylbiphenyl (1449574-70-2) → 4-methylphenanthrene (832-64-4)

Guidance literature:

With silver hexafluoroantimonate; C₃₆H₆₁AuClN₄P⁽²⁺⁾*2BF₄^(1-); In dichloromethane; at 20 ℃; Inert atmosphere;

DOI:10.1021/ja411146x

Reference yield: 75.0%

C15H14O → 4-methylphenanthrene (832-64-4)

Guidance literature:

With 5,10,15,20-tetraphenylporphyrinatochromium(III) hexafluoroantimonate; In 1,2-dichloro-ethane; at 100 ℃; for 2h; Inert atmosphere; Sealed tube;

DOI:10.1055/s-0033-1339710

upstream raw materials:

4-methyl-phenanthrene-1,2-dicarboxylic acid-anhydride

1,2,3,4-tetrahydro-4-methyl-4-phenanthrenol

C₁₅H₁₃Br

4-methyl-1,2-dihydro-phenanthrene

Downstream raw materials:

4-Phenanthrencarbaldehyd

3-methylphenathrene

phenanthrene

4‐phenanthrenemethanol

Refernces

• 1、 Akhmetov, Vladimir,Amsharov, Konstantin,Feofanov, Mikhail,Sharapa, Dmitry I.. "Alumina-Mediated π-Activation of Alkynes". . p. 15420 - 15426. Retrieved 2021/09/30.
• 2、 Zhao, Zhensheng,Britt, Liam H.,Murphy, Graham K.. "Oxidative, Iodoarene-Catalyzed Intramolecular Alkene Arylation for the Synthesis of Polycyclic Aromatic Hydrocarbons". . p. 17002 - 17005. Retrieved 2018/11/01.