Tetradecyltrichlorosilane

Base Information

• Chemical Name: Tetradecyltrichlorosilane
• CAS No.: 18402-22-7
• Molecular Formula: C14H29Cl3Si
• Molecular Weight: 331.829
• Hs Code.: 29319000
• European Community (EC) Number: 678-409-4
• NSC Number: 136541
• UNII: YST9DRT2MD
• DSSTox Substance ID: DTXSID20885033
• Nikkaji Number: J208.995E
• Wikidata: Q82863663
• Mol file: 18402-22-7.mol

Synonyms:18402-22-7;Tetradecyltrichlorosilane;n-Tetradecyltrichlorosilane;Trichloro(tetradecyl)silane;Silane, trichlorotetradecyl-;Trichlorotetradecylsilane;YST9DRT2MD;NSC 136541;NSC-136541;EC 678-409-4;Myristyltrichlorosilane;NSC136541;Trichloromyristylsilane;UNII-YST9DRT2MD;Trichlorotetradecyl-Silane;Silane,trichlorotetradecyl-;C14H29Cl3Si;Trichloro(tetradecyl)silane #;SCHEMBL443492;C14-H29-Cl3-Si;DTXSID20885033;MFCD00051440;AKOS025402712;C(CCCCCCCCCCC)CC[Si](Cl)(Cl)Cl;CS-0435533;T0924

Chemical Property of Tetradecyltrichlorosilane

Chemical Property:

• Vapor Pressure: 0.000794mmHg at 25°C
• Refractive Index: 1.4565
• Boiling Point: 315.8 °C at 760 mmHg
• Flash Point: 156.5 °C
• PSA: 0.00000
• Density: 1.006 g/cm³
• LogP: 7.34280
• Sensitive.: Moisture Sensitive
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 0
• Rotatable Bond Count: 12
• Exact Mass: 330.110411
• Heavy Atom Count: 18
• Complexity: 169

Purity/Quality:

98% ^*data from raw suppliers

Trichlorotetradecylsilane >93.0%(GC) ^*data from reagent suppliers

Safty Information:

• Pictogram(s): R34:Causes burns.
• Hazard Codes: R34:Causes burns.
• Statements: 34
• Safety Statements: 26-36/37/39-45-23

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CCCCCCCCCCCCCC[Si](Cl)(Cl)Cl

Technology Process of Tetradecyltrichlorosilane

There total 5 articles about Tetradecyltrichlorosilane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 50.0%

tetrachlorosilane (10026-04-7,53609-55-5) + tetradecylmagnesium bromide (88303-25-7) → (n-C14H29)SiCl3 (18402-22-7)

Guidance literature:

In not given;

DOI:10.1021/ja01182a014

Reference yield:

(E)-7-tetradecene (41446-63-3) → (n-C14H29)SiCl3 (18402-22-7)

Guidance literature:

With dihydrogen hexachloroplatinate(IV) hexahydrate; trichlorosilane; In isopropyl alcohol; at 0 - 100 ℃; for 20h; Inert atmosphere; Schlenk technique; Sealed tube;

DOI:10.1021/acs.orglett.9b02695

Reference yield:

tetradecylmagnesium bromide (88303-25-7) → (n-C14H29)SiCl3 (18402-22-7)

Guidance literature:

With tetrachlorosilane; diethyl ether;

upstream raw materials:

1-tetradecene

tetradecylmagnesium bromide

n-tetradecylmagnesium chloride

tetrachlorosilane

Downstream raw materials:

1-tetradecene

me3Si(n-C14H29)

trimethoxy(tetradecyl)silane

Refernces

• 1、 Aisa, A. M. A.,Kraetzer, D.,Richter, H.. "Synthesis and characterization of biophilic siliconorganic compounds". . p. 751 - 758. Retrieved 2007/10/03.