3-[Carbamoyloxymethyl(dimethyl)silyl]propyl carbamate

Base Information

• Chemical Name: 3-[Carbamoyloxymethyl(dimethyl)silyl]propyl carbamate
• CAS No.: 3124-47-8
• Molecular Formula: C₈H₁₈N₂O₄Si
• Molecular Weight: 234.327
• NSC Number: 96813
• DSSTox Substance ID: DTXSID40294486
• Wikidata: Q82033824
• Mol file: 3124-47-8.mol

Synonyms:3124-47-8;3-[carbamoyloxymethyl(dimethyl)silyl]propyl carbamate;NSC96813;DTXSID40294486;NSC-96813

Chemical Property of 3-[Carbamoyloxymethyl(dimethyl)silyl]propyl carbamate

Chemical Property:

• Vapor Pressure: 1.92E-07mmHg at 25°C
• Boiling Point: 425.4°Cat760mmHg
• Flash Point: 211.1°C
• Density: 1.112g/cm³
• Hydrogen Bond Donor Count: 2
• Hydrogen Bond Acceptor Count: 4
• Rotatable Bond Count: 8
• Exact Mass: 234.10358359
• Heavy Atom Count: 15
• Complexity: 233

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C[Si](C)(CCCOC(=O)N)COC(=O)N

Technology Process of 3-[Carbamoyloxymethyl(dimethyl)silyl]propyl carbamate

There total 3 articles about 3-[Carbamoyloxymethyl(dimethyl)silyl]propyl carbamate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

γ-Hydroxypropyl-chlormethyl-dimethyl-silan (18171-24-9) → Hydroxymethyl-(3-hydroxy-propyl)-dimethyl-silan-dicarbamat (3124-47-8)

Guidance literature:

Multi-step reaction with 3 steps

1: KOAc

2: LiAlH₄

3: (i) Py, (ii) liq. NH₃

With lithium aluminium tetrahydride; potassium acetate;

DOI:10.1021/jm00329a012

Reference yield:

Acetoxymethyl-<3-acetoxy-propyl>-dimethyl-silan (2917-57-9) → Hydroxymethyl-(3-hydroxy-propyl)-dimethyl-silan-dicarbamat (3124-47-8)

Guidance literature:

Multi-step reaction with 2 steps

1: LiAlH₄

2: (i) Py, (ii) liq. NH₃

With lithium aluminium tetrahydride;

DOI:10.1021/jm00329a012

Reference yield:

Hydroxymethyl-<3-hydroxy-propyl>-dimethyl-silan (2917-49-9) + phenyl chloroformate (1885-14-9) → Hydroxymethyl-(3-hydroxy-propyl)-dimethyl-silan-dicarbamat (3124-47-8)

Guidance literature:

Multistep reaction; (i) Py, (ii) liq. NH₃;

DOI:10.1021/jm00329a012

upstream raw materials:

Hydroxymethyl-<3-hydroxy-propyl>-dimethyl-silan

phenyl chloroformate

γ-Hydroxypropyl-chlormethyl-dimethyl-silan

Acetoxymethyl-<3-acetoxy-propyl>-dimethyl-silan

Refernces