Tetrachloroaurate

Base Information

• Chemical Name: Tetrachloroaurate
• CAS No.: 14337-12-3
• Molecular Formula: AuCl₄
• Molecular Weight: 338.779
• DSSTox Substance ID: DTXSID601014503
• Nikkaji Number: J276.358C
• Mol file: 14337-12-3.mol

Synonyms:Tetrachloroaurate;14337-12-3;Aurate(1-), tetrachloro-, (SP-4-1)-;gold(3+);tetrachloride;Aurate(1-), tetrachloro-;AuCl4;Au-Cl4;Tetrachloroaurate (III);DTXSID601014503

Chemical Property of Tetrachloroaurate

Chemical Property:

• PSA: 0.00000
• LogP: -11.98650
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 4
• Rotatable Bond Count: 0
• Exact Mass: 338.839031
• Heavy Atom Count: 5
• Complexity: 0

Purity/Quality:

97% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: [Cl-].[Cl-].[Cl-].[Cl-].[Au+3]

Technology Process of Tetrachloroaurate

There total 62 articles about Tetrachloroaurate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

trichloro(4-cyanopyridine)gold(III) (14038-56-3) + chloride (16887-00-6) → pyridine-4-carbonitrile (100-48-1) + tetrachloroaurate(III)(1-) (14337-12-3)

Guidance literature:

In methanol; dichloromethane; water; addn. of Au-complex in dichloromethane to LiCl+HClO4 in methanol:water (95:5 v/v) at 25 °C; detected by UV; Kinetics;

DOI:10.1039/DT9910000307

Reference yield:

trichloro(4-aminopyridine)gold(III) (1089196-28-0) + chloride (16887-00-6) → 4-aminopyridine (504-24-5) + tetrachloroaurate(III)(1-) (14337-12-3)

Guidance literature:

With CH₃SO₃H; In methanol; acetone; Au complex in acetone added to a methanolic soln. of Cl(1-) at 25°C in the presence of 0.1 M/l CH3SO3H; not isolated, detected by UV; Kinetics;

DOI:10.1002/ejic.200700457

Reference yield:

trichloro(2,4-dimethylthiazole)gold(III) (132963-53-2) + chloride (16887-00-6) → 2,4-dimethylthiazole (541-58-2) + tetrachloroaurate(III)(1-) (14337-12-3)

Guidance literature:

In methanol; dichloromethane; water; addn. of Au-complex in dichloromethane to LiCl+HClO4 in methanol:water (95:5 v/v) at 25 °C; detected by UV; Kinetics;

DOI:10.1039/DT9910000307

upstream raw materials:

chloride

[AuCl₃NH₃]

dichloro(pyridine-2-carboxylato)gold(III)

hydrogenchloride

Downstream raw materials:

tin(IV)

Refernces

• 1、 Watkins, John D.,Hotchen, Christopher E.,Mitchels, John M.,Marken, Frank. "Decamethylferrocene redox chemistry and gold nanowire electrodeposition at salt crystal|electrode|nonpolar organic solvent contacts". . p. 2616 - 2620. Retrieved 2012.
• 2、 Khisamutdinov,Murinov,Shitikova. "Extraction of gold(III), palladium(II), and platinum(IV) by 1-[2-(2,4-dichlorophenyl)-4-propyl-1,3-dioxolan-2-ylmethyl]-1H-1,2,4-triazole from hydrochloric acid solutions". . p. 969 - 978. Retrieved 2007.
• 3、 Annibale, Giuliano,Natile, Giovanni,Cattalini, Lucio. "". . . Retrieved 1976.
• 4、 Gui, Wenjun,Shi, Yun,Wei, Jia,Zhang, Zhifang,Li, Ping,Xu, Xia,Cui, Yanjun,Yang, Ying. "Synthesis of: N-(3-aminopropyl)imidazole-based poly(ionic liquid) as an adsorbent for the selective recovery of Au(III) ions from aqueous solutions". . p. 20387 - 20395. Retrieved 2020.
• 5、 Annibale, Giuliano,Natile, Giovanni,Pitteri, Bruno,Cattalini, Lucio. "". . . Retrieved 1978.
• 6、 Annibale, Giuliano,Canovese, Luciano,Cattalini, Lucio,Marangoni, Giampaolo,Michelon, Gianni,Tobe, Martin L.. "DISPLACEMENT BY CHLORIDE OF PYRIDINE-2-CARBOXYLATE FROM DICHLORO(PYRIDINE-2-CARBOXYLATO)GOLD(III) IN ACIDIC SOLUTION; THE POSITION OF RING OPENING". . p. 1641 - 1646. Retrieved 1984.
• 7、 Cattalini, Lucio,Chessa, Gavino,Marangoni, Giampaolo,Pitteri, Bruno,Tobe, Martin L.. "The Preparation of Trichloro(phenyl 2-pyridylmethyl sulphoxide)gold(III) and the Kinetics and Equilibria of its Formation and Subsequent Reactions". . p. 2091 - 2094. Retrieved 1985.