METHYL-D1 ALCOHOL

Base Information

• Chemical Name: METHYL-D1 ALCOHOL
• CAS No.: 4206-31-9
• Molecular Formula: CH3 D O
• Molecular Weight: 33.0342
• Mol file: 4206-31-9.mol

Synonyms:Methanol-d1;Methyl-d alcohol

Chemical Property of METHYL-D1 ALCOHOL

Chemical Property:

• Refractive Index: n20/D 1.326(lit.)
• Boiling Point: 48.1°Cat760mmHg
• Flash Point: 11.1°C
• PSA: 20.23000
• Density: 0.776g/cm³
• LogP: -0.39150

Purity/Quality:

Methanol-d ^*data from reagent suppliers

Safty Information:

• Hazard Codes: F,T
• Statements: 11-23/25-39/23/24/25-23/24/25
• Safety Statements: 7-16-24-45-36/37

MSDS Files:

SDS file from LookChem

Useful:

• Uses: Methanol-d is an isotope labelled version of Methanol (M276585). Methanol (M276585) is a common chemical reagent in organic synthesis participating in a variety of reactions. Methanol is a bioactive component with antimicrobial activities.

Technology Process of METHYL-D1 ALCOHOL

There total 3 articles about METHYL-D1 ALCOHOL which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

d7-N,N-dimethylformamide (4472-41-7,185990-36-7) → deuteriomethanol (4206-31-9)

Guidance literature:

With bis(cyclopentadienyl)titanium dichloride; sodium tetrahydroborate; Yield given. Multistep reaction; 1.) 96 deg C, 1 h;

DOI:10.1021/jo00070a045

Reference yield:

formaldehyd (50-00-0,30525-89-4,61233-19-0) → deuteriomethanol (4206-31-9)

Guidance literature:

With sodium borodeuteride;

DOI:10.1016/0584-8539(82)80161-X

Reference yield:

→ deuteriomethanol (4206-31-9)

Guidance literature:

upstream raw materials:

formaldehyd

d₇-N,N-dimethylformamide

Downstream raw materials:

<2H1>methyl iodide

2,4-dimethylquinoline

Co(C₅H₅)(P(C₆H₅)3)CH₂CH₂CH⁽²⁾HC(O)

Co(C₅H₅)(P(C₆H₅)3)CH₂CH₂CH⁽²⁾HC(O)

Refernces

• 1、 Liu, Yumin,Schwartz, Jeffrey. "The Species Prepared from Sodium Borohydride and N,N-Dimethylformamide Reduces or Dimethylaminates Organic Halides". . p. 5005 - 5007. Retrieved 2007/10/02.