Bis(4-methylphenyl)iodonium hexafluorophosphate

Base Information

• Chemical Name: Bis(4-methylphenyl)iodonium hexafluorophosphate
• CAS No.: 60565-88-0
• Molecular Formula: C14H14I^.F6P
• Molecular Weight: 454.134
• European Community (EC) Number: 262-301-5
• DSSTox Substance ID: DTXSID10976005
• Mol file: 60565-88-0.mol

Synonyms:60565-88-0;Bis(4-methylphenyl)iodonium hexafluorophosphate;bis(4-methylphenyl)iodanium;hexafluorophosphate;Iodonium bis(4-methylphenyl) Hexafluorophosphate;Bis(p-tolyl)iodonium hexafluorophosphate;Iodonium bis(4-methylphenyl)hexafluorophosphate;DTXSID10976005;LHLVGWWCRPPKBC-UHFFFAOYSA-N;MFCD06656584;AKOS015901839;di-p-tolyliodo-nium hexafluorophosphate;dip-tolyliodonium hexafluorophosphate(V);AS-15555;NS00054648;A913710;Bis(4-methylphenyl)iodanium hexafluoridophosphate(1-);Bis(4-methylphenyl)iodonium hexafluorophosphate, 98%

Chemical Property of Bis(4-methylphenyl)iodonium hexafluorophosphate

Chemical Property:

• Appearance/Colour: White powder
• Melting Point: 175-180oC
• PSA: 13.59000
• LogP: 3.81420
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 7
• Rotatable Bond Count: 2
• Exact Mass: 453.97820
• Heavy Atom Count: 22
• Complexity: 217

Purity/Quality:

99% ^*data from raw suppliers

Bis(4-methylphenyl)iodonium hexafluorophosphate ^*data from reagent suppliers

Safty Information:

• Pictogram(s): C
• Hazard Codes: C
• Statements: 34
• Safety Statements: 26-36/37/39-45

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CC1=CC=C(C=C1)[I+]C2=CC=C(C=C2)C.F[P-](F)(F)(F)(F)F

Technology Process of Bis(4-methylphenyl)iodonium hexafluorophosphate

There total 1 articles about Bis(4-methylphenyl)iodonium hexafluorophosphate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

bis(4-methylphenyl)iodonium trifluoromethanesulfonate (123726-16-9) → bis(4-methylphenyl)iodonium hexafluorophosphate (60565-88-0)

Guidance literature:

With potassium hexafluorophosphate; In acetonitrile; for 24h; Inert atmosphere; Sealed tube;

DOI:10.1021/ol501655g

Reference yield: 95.0%

bis(4-methylphenyl)iodonium hexafluorophosphate (60565-88-0) + anthranilic acid nitrile (1885-29-6) → 2-(3-(4-methylphenyl)-4-imino-3,4-dihydroquinazoline)-2-aniline

Guidance literature:

In 1,2-dichloro-ethane; at 20 - 120 ℃; for 48h; Inert atmosphere;

Reference yield: 90.0%

(5-methylhex-1-yn-1-yl)benzene (62707-15-7) + bis(4-methylphenyl)iodonium hexafluorophosphate (60565-88-0) → 1-(3,3-dimethyl-2-phenylcyclopent-1-en-1-yl)-4-methylbenzene (1618681-44-9)

Guidance literature:

bis(4-methylphenyl)iodonium hexafluorophosphate; With copper(II) bis(trifluoromethanesulfonate); at 80 ℃; for 1h; Inert atmosphere; Sealed tube; Schlenk technique;

(5-methylhex-1-yn-1-yl)benzene; In 1,2-dichloro-ethane; at 60 ℃; for 12h; Inert atmosphere; Sealed tube; Schlenk technique;

DOI:10.1021/ol501655g

upstream raw materials:

bis(4-methylphenyl)iodonium trifluoromethanesulfonate

Downstream raw materials:

4-tolyl iodide

di(n-butyl)(p-tolyl)phosphine

(4,4'-dimethyl-1,1'-biphenyl)

3,4'-dimethylbiphenyl

Refernces