dimethylazanium;N,N-dimethylcarbamate

Base Information

• Chemical Name: dimethylazanium;N,N-dimethylcarbamate
• CAS No.: 4137-10-4
• Molecular Formula: C5H14N2O2
• Molecular Weight: 134.178
• Hs Code.: 29215990
• Mol file: 4137-10-4.mol

Synonyms:SCHEMBL1644200;JIYXHCMRGZVYMA-UHFFFAOYSA-N;AKOS024389636

Chemical Property of dimethylazanium;N,N-dimethylcarbamate

Chemical Property:

• Appearance/Colour: clear colorless to light yellow liquid
• Vapor Pressure: 2.83mmHg at 25°C
• Melting Point: °C
• Refractive Index: n20/D 1.454(lit.)
• Boiling Point: 144.7 °C at 760 mmHg
• Flash Point: 41.3 °C
• PSA: 52.57000
• Density: 1.05 g/mL at 25 °C(lit.)
• LogP: 0.45250
• Storage Temp.: 2-8°C
• Hydrogen Bond Donor Count: 1
• Hydrogen Bond Acceptor Count: 2
• Rotatable Bond Count: 0
• Exact Mass: 134.105527694
• Heavy Atom Count: 9
• Complexity: 57.1

Purity/Quality:

98%,99%, ^*data from raw suppliers

Dimethylammonium dimethylcarbamate ^*data from reagent suppliers

Safty Information:

• Pictogram(s): Xi
• Hazard Codes: Xi
• Statements: 10-36/37/38
• Safety Statements: 26-36

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C[NH2+]C.CN(C)C(=O)[O-]
• Uses: Dimethylammonium dimethylcarbamate is an ionic liquid primarily used as a solvent.? ;For synthesis of calixarene-based ketocyanine fluorophores1? ;Distillation extraction of tannins from plant materials2? ;Electrodeposition of silver3 or of lead on glassy carbon and mercury film electrodes4? ;Synthesis of Ag and Au nanostructures5? ;Reusable reaction medium for synthesis of monoarylidene cyclopentanones6 Ionic liquid primarily used as a solvent.For synthesis of calixarene-based ketocyanine fluorophoresDistillation extraction of tannins from plant materialsElectrodeposition of silver or of lead on glassy carbon and mercury film electrodesSynthesis of Ag and Au nanostructuresReusable reaction medium for synthesis of monoarylidene cyclopentanones

Technology Process of dimethylazanium;N,N-dimethylcarbamate

There total 3 articles about dimethylazanium;N,N-dimethylcarbamate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

methanol (67-56-1) + carbon dioxide (124-38-9,18923-20-1) → DIMCARB (4137-10-4)

Guidance literature:

methanol; With ammonium carbonate; aluminum oxide; at 350 ℃; for 3h;

carbon dioxide; at 20 - 80 ℃; under 3750.38 Torr; Further stages.;

DOI:10.1002/jlcr.1467

Reference yield:

carbon dioxide (124-38-9,18923-20-1) + dimethyl amine (124-40-3) → DIMCARB (4137-10-4)

Guidance literature:

In chloroform; Thermodynamic data; Equilibrium constant; ΔG(act.) value for the equilibrium;

Reference yield:

N,N-dimethylcarbamic acid (7260-94-8) → carbon dioxide (124-38-9,18923-20-1) + DIMCARB (4137-10-4)

Guidance literature:

at -50 ℃; Mechanism; equilibrium investigation;

upstream raw materials:

N,N-dimethylcarbamic acid

carbon dioxide

dimethyl amine

methanol

Downstream raw materials:

N,N-Dimethyl-2-pyridin-3-yl-thioacetamide

N,N-dimethylthiobenzamide

2-(2,5-Dimethyl-thiophen-3-yl)-N,N-dimethyl-thioacetamide

N,N-dimethylcarbamic acid

Refernces

• 1、 Adelwoehrer, Christian,Yoneda, Yuko,Nakatsubo, Fumiaki,Rosenau, Thomas. "Synthesis of the perdeuterated cellulose solvents N-methylmorpholine N-oxide (NMMO-d11) and N,N-dimethylacetamide (DMAC-d9)". . p. 28 - 32. Retrieved 2008/09/18.
• 2、 Schroth, Werner,Andersch, Joerg. "Dimethylammonium Dimethylcarbamate - A Useful Reagent for the Willgerodt-Kindler Reaction". . p. 202 - 204. Retrieved 2007/10/02.