Methyl phenylsulfonylacetate

Base Information Edit

Chemical Name:Methyl phenylsulfonylacetate
CAS No.:34097-60-4
Molecular Formula:C9H10O4S
Molecular Weight:214.242
Hs Code.:29309090
DSSTox Substance ID:DTXSID50872012
Nikkaji Number:J150.047C
Wikidata:Q106902902
ChEMBL ID:CHEMBL162146
Mol file:34097-60-4.mol

Synonyms:Methyl phenylsulfonylacetate;34097-60-4;methyl 2-(phenylsulfonyl)acetate;methyl 2-(benzenesulfonyl)acetate;Methyl phenylsulfonyl acetate;METHYLPHENYLSULFONYLACETATE;MFCD00007555;Benzenesulfonyl-acetic acid methyl ester;Methyl benzenesulfonylacetate;SCHEMBL602;Methyl (phenylsulfonyl)acetate;CHEMBL162146;Methyl A-(phenylsulfonyl)acetate;DTXSID50872012;methyl 2-(phenylsulphonyl)acetate;Methyl phenylsulfonylacetate, 97%;Methyl alpha-(phenylsulfonyl)acetate;AKOS009156965;phenylsulfonyl acetic acid methyl ester;Phenylsulfonylacetic Acid Methyl Ester;phenylsulfonylacetic acid, methyl ester;Methyl .alpha.-(phenylsulfonyl)acetate;AS-60908;SY049693;2-(Phenylsulfonyl)acetic acid, methyl ester;CS-0133099;FT-0628791;P1353;D71093;J-019447

Suppliers and Price of Methyl phenylsulfonylacetate

Supply Marketing:Edit

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

TRC
Methyl2-(Phenylsulfonyl)acetate
50mg
$ 45.00

TCI Chemical
Methyl Phenylsulfonylacetate >95.0%(GC)
5g
$ 45.00

TCI Chemical
Methyl Phenylsulfonylacetate >95.0%(GC)
25g
$ 136.00

Sigma-Aldrich
Methyl phenylsulfonylacetate 97%
10g
$ 52.20

Oakwood
Methyl α-(phenylsulfonyl)acetate
500g
$ 1000.00

Oakwood
Methyl α-(phenylsulfonyl)acetate
100g
$ 220.00

Oakwood
Methyl α-(phenylsulfonyl)acetate
25g
$ 59.00

Oakwood
Methyl α-(phenylsulfonyl)acetate
1g
$ 10.00

Oakwood
Methyl α-(phenylsulfonyl)acetate
5g
$ 15.00

Matrix Scientific
Methyl alpha-(phenylsulfonyl)acetate 97%
5g
$ 14.00

Total 49 raw suppliers

Chemical Property of Methyl phenylsulfonylacetate Edit

Chemical Property:

Appearance/Colour:white to light yellow solid.
Vapor Pressure:0mmHg at 25°C
Melting Point:30 °C
Refractive Index:n20/D 1.535(lit.)
Boiling Point:445.142 °C at 760 mmHg
Flash Point:180.623 °C
PSA：68.82000
Density:1.277 g/cm³
LogP:1.71410
Storage Temp.:Sealed in dry,Room Temperature
Water Solubility.:Insoluble in water.
XLogP3:1.1
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:4
Rotatable Bond Count:4
Exact Mass:214.02997997
Heavy Atom Count:14
Complexity:282

Purity/Quality:

98% ^*data from raw suppliers

Methyl2-(Phenylsulfonyl)acetate ^*data from reagent suppliers

Safty Information:

Pictogram(s):
Hazard Codes:
Statements: 10
Safety Statements: 23-24/25-43-36/37/39-15/16

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

Chemical Classes:Other Classes -> Benzenesulfonic Acid Derivatives
Canonical SMILES:COC(=O)CS(=O)(=O)C1=CC=CC=C1
Uses Methyl phenylsulfonylacetate has been used in a key step during the synthesis of (-)-hybridalactone, marine eicosanoid isolated from the red alga Laurencia hybrida, in dehydrative alkylation of alcohols under modified Mitsunobu conditions followed by desulfonylation using magnesium, in three step synthesis of 2-(hydroxymethyl)indene.

Technology Process of Methyl phenylsulfonylacetate

There total 21 articles about Methyl phenylsulfonylacetate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 96.0%

: 873-55-2
sodium benzenesulfonate

: 96-32-2
bromoacetic acid methyl ester

: 34097-60-4
methyl benzenesulfonylacetate

Guidance literature:: In ethanol; for 24h; Reflux;

Reference yield: 96.0%

: 96-32-2
bromoacetic acid methyl ester

: 618-41-7
Benzenesulfinic acid

: 34097-60-4
methyl benzenesulfonylacetate

Guidance literature:

Reference yield: 95.0%

: 14090-83-6
methyl 2-phenylsulfinylacetate

: 34097-60-4
methyl benzenesulfonylacetate

Guidance literature:: With 2,2,4,4,6,6-hexachloro-1,3,5-triaza-2,4,6-triphosphorine; dihydrogen peroxide; at 25 ℃; for 0.216667h; chemoselective reaction; Neat (no solvent);
DOI:10.1021/jo1011784