Magnesium 2-methylpropane chloride

Base Information

• Chemical Name: Magnesium 2-methylpropane chloride
• CAS No.: 677-22-5
• Molecular Formula: C4H9ClMg
• Molecular Weight: 116.873
• Hs Code.: 29319090
• DSSTox Substance ID: DTXSID00987044
• Mol file: 677-22-5.mol

Synonyms:magnesium 2-methylpropane chloride;SCHEMBL474048;DTXSID00987044;AKOS032949747;FT-0654205;A835863;Magnesium chloride 2-methylpropan-2-ide (1/1/1)

Chemical Property of Magnesium 2-methylpropane chloride

Chemical Property:

• Appearance/Colour: clear faint grey to grey, grey-brown or light
• Melting Point: 46oC to 50oC
• Boiling Point: 34 °F
• Flash Point: 34 °F
• PSA: 0.00000
• Density: 0.931 g/mL at 25 °C
• LogP: 2.44360
• Storage Temp.: 2-8°C
• Sensitive.: Air & Moisture Sensitive
• Water Solubility.: Miscible with alcohol and water.
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 2
• Rotatable Bond Count: 0
• Exact Mass: 116.0243197
• Heavy Atom Count: 6
• Complexity: 4.8

Purity/Quality:

99% purity ^*data from raw suppliers

tert-ButylmagnesiumChloride(2.0MinDiethylEther) ^*data from reagent suppliers

Safty Information:

• Pictogram(s): F+;C;F
• Hazard Codes: F+,C,F
• Statements: 12-14/15-19-22-34-66-67-15-11-14-37-17-40
• Safety Statements: 9-16-26-29-33-36/37/39-43-45

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

• Canonical SMILES: C[C-](C)C.[Mg+2].[Cl-]
• Uses: tert-Butylmagnesium chloride is a Grignard reagent used in organic synthesis. It is also involved in copper-catalyzed cross-coupling reaction with primary-alkyl halides.

Technology Process of Magnesium 2-methylpropane chloride

There total 7 articles about Magnesium 2-methylpropane chloride which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

→ tertiary butyl chloride (507-20-0) + tert-butylmagnesium chloride (677-22-5)

Guidance literature:

Reference yield:

tertiary butyl chloride (507-20-0) + magnesium (7439-95-4) → tert-butylmagnesium chloride (677-22-5)

Guidance literature:

In tetrahydrofuran;

Reference yield:

tertiary butyl chloride (507-20-0) → tert-butylmagnesium chloride (677-22-5)

Guidance literature:

With magnesium anthracene * 3 THF; Product distribution; multistep reaction; other procedures for the preparation of Mg^*; other solvents;

upstream raw materials:

tertiary butyl chloride

9,10-dihydro-9,10-anthracendiyl-tris(THF)magnesium

n-propyltrichlorosilane

magnesium

Downstream raw materials:

3,3-dimethylbutanol

1-chloro-3-hydroxypropane

tetramethyl-2,2,3,3 butane

Isobutane

Refernces

• 1、 Schnegelsberg, Christoph,Bachmann, Sebastian,Kolter, Marlene,Auth, Thomas,John, Michael,Stalke, Dietmar,Koszinowski, Konrad. "Association and Dissociation of Grignard Reagents RMgCl and Their Turbo Variant RMgC?LiCl". supporting information. p. 7752 - 7762. Retrieved 2016/06/08.
• 2、 -. "AN IMPROVED PROCESS FOR THE PREPARATION OF MORPHINANE ANALOGUES". Page/Page column 28. . Retrieved 2009/10/30.