Aluminum,4-pentanedionato)-

Base Information

• Chemical Name: Aluminum,4-pentanedionato)-
• CAS No.: 13963-57-0
• Molecular Formula: C15H21AlO6
• Molecular Weight: 324.31
• Hs Code.: 29420000
• NSC Number: 52330,4650
• Mol file: 13963-57-0.mol

Synonyms:Aluminum,4-pentanedionato)-;Aluminum,4-pentanedionato-O,O')-, (OC-6-11)-;WLN: D6O-AL-O BDJ D1 F1 B-& BD6O-AL-O BDJ D1 F1 B-& BD6O-AL-O BDJ D1 F1;NSC4650;NSC52330;NSC-52330

Chemical Property of Aluminum,4-pentanedionato)-

Chemical Property:

• Appearance/Colour: white to yellow powder or crystals
• Vapor Pressure: 0Pa at 25℃
• Melting Point: 190-193 °C(lit.)
• Boiling Point: 315°C(lit.)
• Flash Point: 314-316°C
• PSA: 78.90000
• Density: 1.27 g/cm³
• LogP: 2.88030
• Storage Temp.: Store below +30°C.
• Solubility.: 3g/l
• Water Solubility.: 2.5 g/L (20 ºC)
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 6
• Rotatable Bond Count: 0
• Exact Mass: 327.1388269
• Heavy Atom Count: 22
• Complexity: 314

Purity/Quality:

99% ^*data from raw suppliers

Tris(2,4-pentanedionato)aluminum(III) >99.0%(T) ^*data from reagent suppliers

Safty Information:

• Pictogram(s): T
• Hazard Codes: T
• Statements: 25-36/37/38-36-43
• Safety Statements: 26-36/37/39-45-28A-36/37

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

• Canonical SMILES: CC(=O)CC(=O)C.CC(=O)CC(=O)C.CC(=O)CC(=O)C.[Al]
• Uses: Aluminum acetylacetonate is an important organic intermediate (building block) to synthetize substituted acetylacetonate products. Deposition of aluminum, catalyst. Alumunium acetylacetonate may be used to prepare transparent superhydrophobic boehmite and silica films by sublimation, to deposit alumunium oxide films by chemical vapor deposition, to deposit alumunium oxide films by chemical vapor deposition, as a catalyst.

Technology Process of Aluminum,4-pentanedionato)-

There total 10 articles about Aluminum,4-pentanedionato)- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 91.0%

aluminum hydroxide + acetylacetone (123-54-6,81235-32-7) → aluminium acetylacetonate (13963-57-0)

Guidance literature:

at 0 - 50 ℃; for 0.75h;

Reference yield:

lithium aluminium tetrahydride (16853-85-3) + nickel(II) acetylacetonate (3264-82-2) → aluminium hydride + nickel (7440-02-0) + aluminium acetylacetonate (13963-57-0) + lithium pentane-2,4-dionate (18115-70-3)

Guidance literature:

In tetrahydrofuran; benzene; byproducts: H2; various product ratios at various reactant ratios; not isolated, detected by GLC, UV, IR;

DOI:10.1134/S1070427210110030

Reference yield:

acetyl chloride (75-36-5) → aluminium acetylacetonate (13963-57-0) + acetylacetone (123-54-6,81235-32-7)

Guidance literature:

upstream raw materials:

acetylacetone

acetyl chloride

copper bis(tetraisopropoxyaluminate)

aluminium trichloride

Refernces

• 1、 Dhara,Panigrahi,Magudapathy,Nair. "Low field magnetoconductance studies in aggregated Al nano-clusters". . p. 284 - 287. Retrieved 2001.
• 2、 -. "PROCESS FOR THE PREPARATION OF METAL ACETYLACETONATES". Page 9-10. . Retrieved 2008/06/13.