1-Butanol, 4-(ethenyloxy)-

Base Information

• Chemical Name: 1-Butanol, 4-(ethenyloxy)-
• CAS No.: 17832-28-9
• Molecular Formula: C6H12O2
• Molecular Weight: 116.16
• Hs Code.: 2909 49 80
• European Community (EC) Number: 241-793-5
• UNII: 8LGM5RZX0N
• DSSTox Substance ID: DTXSID6044854
• Nikkaji Number: J51.553A
• Wikidata: Q27270719
• RXCUI: 2289429
• ChEMBL ID: CHEMBL3182123
• Mol file: 17832-28-9.mol

Synonyms:17832-28-9;4-(Vinyloxy)butan-1-ol;1-Butanol, 4-(ethenyloxy)-;1,4-Butanediol vinyl ether;4-Hydroxybutyl vinyl ether;4-(Ethenyloxy)butan-1-ol;4-ethenoxybutan-1-ol;hydroxybutyl vinyl ether;UNII-8LGM5RZX0N;8LGM5RZX0N;4-(Vinyloxy)-1-butanol;DTXSID6044854;EINECS 241-793-5;EC 241-793-5;1,4-Butanediol monovinyl ether;4-Vinyloxybutanol;31244-41-4;(Ethenyloxy)-butanol;HBUVE;HBVE;Hydroxybutyvinyl ether;4-vinyloxy-1-butanol;RAPI-CURE HBVE;4-vinyloxy-butan-1-ol;4-hydroxybutylvinyl ether;4-(ethenyloxy)-1-butanol;4-(VINYLOXY)BUTANOL;SCHEMBL36631;SCHEMBL4287931;4-ETHENYLOXY-1-BUTANOL;CHEMBL3182123;DTXCID4024854;butane-1,4-diol;vinyloxyethylene;Tox21_301676;1-BUTANOL, 4-(VINYLOXY)-;MFCD00080697;AKOS015915491;NCGC00256071-01;CAS-17832-28-9;CS-0077087;FT-0637609;T1796;E81009;EN300-7465856;A812358;Q27270719;1,4-Butanediol vinyl ether, contains 0.01% potassium hydroxide as stabilizer, 99%

Chemical Property of 1-Butanol, 4-(ethenyloxy)-

Chemical Property:

• Appearance/Colour: colorless to yellow liquid
• Vapor Pressure: 0.00263mmHg at 25°C
• Melting Point: -33 °C
• Refractive Index: n20/D 1.444(lit.)
• Boiling Point: 181.5 °C at 760 mmHg
• PKA: 15.04±0.10(Predicted)
• Flash Point: 67.9 °C
• PSA: 29.46000
• Density: 0.917 g/cm³
• LogP: 0.91900
• Storage Temp.: Store at
• Solubility.: 75g/l
• Water Solubility.: 75 g/L (20 ºC)
• XLogP3: 0.9
• Hydrogen Bond Donor Count: 1
• Hydrogen Bond Acceptor Count: 2
• Rotatable Bond Count: 5
• Exact Mass: 116.083729621
• Heavy Atom Count: 8
• Complexity: 52.5

Purity/Quality:

99.9% ^*data from raw suppliers

1,4-Butanediol vinyl ether ^*data from reagent suppliers

Safty Information:

• Pictogram(s): Xn
• Hazard Codes: Xn
• Statements: 20/21/22-36/37/38-22-52/53
• Safety Statements: 26-36-24/25-61

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

• Canonical SMILES: C=COCCCCO

Technology Process of 1-Butanol, 4-(ethenyloxy)-

There total 4 articles about 1-Butanol, 4-(ethenyloxy)- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 69.0%

2-phenylsulfonylmethyl-1,3-dioxepane (425429-11-4) → 4-(vinyloxy)butan-1-ol (17832-28-9)

Guidance literature:

With sodium dihydrogenphosphate; sodium amalgam; In methanol; at 20 ℃;

DOI:10.1016/S0040-4039(01)02195-5

Reference yield: 48.0%

Butane-1,4-diol (110-63-4) + acetylene (74-86-2,25067-58-7) → 4-(vinyloxy)butan-1-ol (17832-28-9) + 1,4-divinyloxybutane (3891-33-6,164978-32-9)

Guidance literature:

With sodium hydroxide; cesium fluoride; at 138 - 140 ℃; for 2h; under 7355.08 - 8826.1 Torr;

DOI:10.1007/s11178-005-0223-x

Reference yield:

Butane-1,4-diol (110-63-4) + acetylene (74-86-2,25067-58-7) → 4-(vinyloxy)butan-1-ol (17832-28-9)

Guidance literature:

With potassium hydroxide; at 130 - 150 ℃; under 14710.2 - 25742.8 Torr;

upstream raw materials:

Butane-1,4-diol

acetylene

2-phenylsulfonylmethyl-1,3-dioxepane

Downstream raw materials:

4-(vinyloxy)butyl 4-methylbenzenesulfonate

methanol

6-acetyl-8-fluoro-2H-1,4-benzoxazin-3(4H)-one

1-{4-[5-(3,5-dichloro-phenyl)-5-trifluoromethyl-4,5-dihydro-isoxazol-3-yl]-2-methyl-phenyl}-ethanone

Refernces

• 1、 Chéry, Florence,Cabianca, Elena,Tatibou?t, Arnaud,De Lucchi, Ottorino,Lindhorst, Thisbe K.,Rollin, Patrick. "Reductive opening of carbohydrate phenylsulfonylethylidene (PSE) acetals". . p. 117 - 124. Retrieved 2015/10/28.