2-(Tert-butylamino)ethyl methacrylate

Base Information

• Chemical Name: 2-(Tert-butylamino)ethyl methacrylate
• CAS No.: 3775-90-4
• Deprecated CAS: 115567-56-1,160928-64-3
• Molecular Formula: C10H19 N O2
• Molecular Weight: 185.266
• Hs Code.: 2922199090
• European Community (EC) Number: 223-228-4
• UN Number: 1760
• UNII: 5ZN7006T63
• DSSTox Substance ID: DTXSID6044931
• Nikkaji Number: J78.369B
• Wikidata: Q27263108
• ChEMBL ID: CHEMBL3182038
• Mol file: 3775-90-4.mol

Synonyms:2-(TERT-BUTYLAMINO)ETHYL METHACRYLATE;3775-90-4;2-(tert-butylamino)ethyl 2-methylprop-2-enoate;tert-Butylaminoethyl methacrylate;Ageflex FM-4;2-tert-Butylaminoethyl methacrylate;2-Propenoic acid, 2-methyl-, 2-[(1,1-dimethylethyl)amino]ethyl ester;N-tert-Butylaminoethyl methacrylate;Methacrylic acid, 2-(tert-butylamino)ethyl ester;HSDB 6111;Tertiary-butylaminoethyl methacrylate;EINECS 223-228-4;BRN 1761825;Ethanol, 2-(tert-butylamino)-, methacrylate (ester);t-butylaminoethyl methacrylate;AI3-61480;DTXSID6044931;UNII-5ZN7006T63;5ZN7006T63;2-((1,1-Dimethylethyl)amino)ethyl 2-methyl-2-propenoate;BUTYLAMINOETHYL METHACRYLATE, TERT-;2-Methyl-2-propenoic acid, 2-((1,1-dimethylethyl)amino)ethyl ester;2-Propenoic acid, 2-methyl-, 2-((1,1-dimethylethyl)amino)ethyl ester;EC 223-228-4;4-04-00-01509 (Beilstein Handbook Reference);2-((1,1-Dimethylethyl)amino )ethyl 2-methyl-2-propenoate;Butyl aminoethyl methacrylate(1.9cp(38 degrees c));2-[(1,1-Dimethylethyl)amino ]ethyl 2-methyl-2-propenoate;SCHEMBL26306;SCHEMBL3293239;CHEMBL3182038;DTXCID4024931;STR05052;Tox21_301718;MFCD00014997;N-(tert-Butylamino)ethyl methacrylate;AKOS024319222;2-(t-Butyl amino) ethanol, methacrylate;NCGC00256136-01;LS-89909;CAS-3775-90-4;2-(tert-Butylamino)ethyl 2-methylacrylate #;B6009;CS-0167870;Ethanol, 2-(tert-butylamino)-, methacrylate;FT-0725650;Methacrylic acid 2-tert-butylaminoethyl ester;E80419;2-(tert-Butylamino)ethyl methacrylate,min. 90%;2-(tert-Butylamino)ethyl methacrylate, stabilized;2-(TERT-BUTYLAMINO)ETHYL METHACRYLATE [HSDB];Q27263108;2-(tert-Butylamino)ethyl methacrylate(stabilizedwithMEHQ);2-(tert-Butylamino)ethyl Methacrylate (stabilized with MEHQ);2-(tert-Butylamino)ethyl Methacrylate, >/=98%,stabilized with MEHQ;2-PROPENOIC ACID, 2-METHYL-, 2-((1,1- DIMETHYLETHYL)AMINO)ETHYL ESTER;2-(tert-Butylamino)ethyl methacrylate, 97%, contains ~1000 ppm monomethyl ether hydroquinone (MEHQ) as inhibitor

Chemical Property of 2-(Tert-butylamino)ethyl methacrylate

Chemical Property:

• Appearance/Colour: clear, colourless up to yellowish liquid
• Vapor Pressure: 0.097mmHg at 25°C
• Melting Point: 100～105℃/12 mm
• Refractive Index: n20/D 1.442(lit.)
• Boiling Point: 248 °C at 760 mmHg
• PKA: 8.99±0.10(Predicted)
• Flash Point: 103.8 °C
• PSA: 38.33000
• Density: 0.914 g/mL at 25 °C(lit.)
• LogP: 1.88470
• Solubility.: Slightly soluble in water
• Water Solubility.: 18g/L at 25℃
• XLogP3: 1.7
• Hydrogen Bond Donor Count: 1
• Hydrogen Bond Acceptor Count: 3
• Rotatable Bond Count: 6
• Exact Mass: 185.141578849
• Heavy Atom Count: 13
• Complexity: 192

Purity/Quality:

99%min ^*data from raw suppliers

2-(tert-Butylamino)ethyl Methacrylate (stabilized with MEHQ) ^*data from reagent suppliers

Safty Information:

• Pictogram(s): Xi
• Hazard Codes: Xi
• Statements: 36/38-43
• Safety Statements: 26

MSDS Files:

SDS file from LookChem

Useful:

• Chemical Classes: Plastics & Rubber -> (Meth)acrylates
• Canonical SMILES: CC(=C)C(=O)OCCNC(C)(C)C

Technology Process of 2-(Tert-butylamino)ethyl methacrylate

There total 2 articles about 2-(Tert-butylamino)ethyl methacrylate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

2-[(1,1-dimethylethyl)amino]-ethanol (4620-70-6) + methacrylic acid methyl ester (80-62-6,114512-63-9,143476-91-9,25188-98-1,9011-14-7) → 2-tert-butylaminoethyl methacrylate (3775-90-4,26716-20-1)

Guidance literature:

DOI:10.1021/jo01358a018

Reference yield:

→ 2-tert-butylaminoethyl methacrylate (3775-90-4,26716-20-1)

Guidance literature:

Methyl-methacrylat, entspr. Alkohol;

Reference yield: 89.0%

2-tert-butylaminoethyl methacrylate (3775-90-4,26716-20-1) + diphenylphosphane (829-85-6) → C22H30NO2P

Guidance literature:

In 2-methyltetrahydrofuran; at 90 ℃; for 4h; regioselective reaction; Inert atmosphere; Sealed tube; Green chemistry;

DOI:10.1039/c9ra04896k

upstream raw materials:

2-[(1,1-dimethylethyl)amino]-ethanol

methacrylic acid methyl ester

Refernces

• 1、 -. "Multi-purpose polymers, methods and compositions". . . Retrieved 2008/06/13.