Stannane, (pentafluorophenyl)triphenyl-

Base Information

• Chemical Name: Stannane, (pentafluorophenyl)triphenyl-
• CAS No.: 1058-08-8
• Molecular Formula: C24H15 F5 Sn
• Molecular Weight: 517.085
• Hs Code.: 2931900090
• NSC Number: 168734
• DSSTox Substance ID: DTXSID60304995
• Mol file: 1058-08-8.mol

Synonyms:Stannane, (pentafluorophenyl)triphenyl-;1058-08-8;(2,3,4,5,6-pentafluorophenyl)-triphenylstannane;NSC168734;DTXSID60304995;NSC-168734

Chemical Property of Stannane, (pentafluorophenyl)triphenyl-

Chemical Property:

• Vapor Pressure: 1.7E-08mmHg at 25°C
• Boiling Point: 468.3°Cat760mmHg
• Flash Point: 237°C
• PSA: 0.00000
• Density: g/cm³
• LogP: 3.75950
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 5
• Rotatable Bond Count: 4
• Exact Mass: 518.011594
• Heavy Atom Count: 30
• Complexity: 480

Purity/Quality:

98%,99%, ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C1=CC=C(C=C1)[Sn](C2=CC=CC=C2)(C3=CC=CC=C3)C4=C(C(=C(C(=C4F)F)F)F)F

Technology Process of Stannane, (pentafluorophenyl)triphenyl-

There total 21 articles about Stannane, (pentafluorophenyl)triphenyl- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 90.0%

pentafluorophenylytterbium bromide (88020-63-7) + triphenyltin chloride (639-58-7) → pentafluorophenyltriphenyltin (1058-08-8)

Guidance literature:

In tetrahydrofuran; Ar atmosphere; addn. of Ph3SnCl in THF to soln. of C6F5YbBr (20°C), stirring (1 h, 20°C); addn. of water, extn. (ether), drying of extract (over MgSO4);

DOI:10.1007/BF00949006

Reference yield: 80.0%

Pentafluorobenzene (363-72-4) + methylytterbium (88068-44-4) + triphenyltin chloride (639-58-7) → hexaphenylditin (1064-10-4) + pentafluorophenyltriphenyltin (1058-08-8)

Guidance literature:

In tetrahydrofuran; Ar atmosphere; addn. of C6HF5 in THF to soln. of MeYbI (20°C), stirring (40 min), addn. of Ph3SnCl in THF, stirring (1 h); addn. of water, extn. (ether), drying of extract (over MgSO4);

DOI:10.1007/BF00949006

Reference yield: 70.0%

pentafluorophenylytterbium bromide (88020-63-7) + triphenyltin chloride (639-58-7) → YbClBr*99(C4H8O) + pentafluorophenyltriphenyltin (1058-08-8)

Guidance literature:

In tetrahydrofuran; at 10°C; the C6F5YbBr (in situ) is treated with (C6H5)3SnCl; warmed to 25°C, after hydrolysis acidified with HCl, septd., extractd. with ether, dried over Na2SO4;; TLC;

DOI:10.1016/0022-328X(85)88124-9

upstream raw materials:

Pentafluorobenzene

methylytterbium

triphenyltin chloride

phenylytterbium iodide

Refernces

• 1、 Doster, Meghan E.,Johnson, Samuel A.. "Carbon-hydrogen bond stannylation and alkylation catalyzed by nitrogen-donor-supported nickel complexes: Intermediates with Ni-Sn bonds and catalytic carbostannylation of ethylene with organostannanes". . p. 4174 - 4184. Retrieved 2013/09/02.
• 2、 Rybakova, L. F.,Syutkina, O. P.,Petrov, E. S.,Shifrina, R. R.,Beletskaya, L. P.. "ORGANIC DERIVATIVES OF DIVALENT YTTERBIUM RYbX IN METALLATION RECTIONS". . p. 1301 - 1303. Retrieved 2007/10/02.