Sodium pentafluoropropionate

Base Information

• Chemical Name: Sodium pentafluoropropionate
• CAS No.: 378-77-8
• Molecular Formula: C3F5NaO2
• Molecular Weight: 186.014
• Hs Code.: 29159000
• European Community (EC) Number: 206-830-1
• DSSTox Substance ID: DTXSID40880141
• Nikkaji Number: J213.603A
• Mol file: 378-77-8.mol

Synonyms:2,2,3,3,3-pentafluoropropanoate;pentafluoropropanoate;perfluoropropanoate;sodium 2,2,3,3,3-pentafluoropropanoate;sodium pentafluoropropanoate;sodium pentafluoropropionate;sodium perfluoropropanoate;sodium

Chemical Property of Sodium pentafluoropropionate

Chemical Property:

• Appearance/Colour: White crystalline powder
• Vapor Pressure: 35.8mmHg at 25°C
• Melting Point: 226-229 °C (dec.)(lit.)
• Boiling Point: 93.5 °C at 760 mmHg
• Flash Point: 10.3 °C
• PSA: 40.13000
• Density: 1.64g/cm³
• LogP: -0.06610
• Sensitive.: Hygroscopic
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 7
• Rotatable Bond Count: 1
• Exact Mass: 185.97161433
• Heavy Atom Count: 11
• Complexity: 152

Purity/Quality:

98%,99%, ^*data from raw suppliers

Sodium pentafluoropropionate 98% ^*data from reagent suppliers

Safty Information:

• Pictogram(s): Xi
• Hazard Codes: Xi
• Statements: 36/37/38
• Safety Statements: 22-24/25

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

• Canonical SMILES: C(=O)(C(C(F)(F)F)(F)F)[O-].[Na+]
• Uses: Sodium pentafluoropropionate may be used in the preparation of:tributyltin pentafluoropropionate (Bu3SnO2CC2F5)trimethyltin pentafluoropropionatenew o-fluoroalkyl-benzenesulfonamide precursors

Technology Process of Sodium pentafluoropropionate

There total 21 articles about Sodium pentafluoropropionate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 92.0%

perfluoropropionic acid methyl ester (378-75-6) + sodium trimethylsilanolate (18027-10-6) → sodium pentafluoropropionate (378-77-8)

Guidance literature:

In dichloromethane;

Reference yield: 92.0%

perfluoropropionic acid methyl ester (378-75-6) → sodium pentafluoropropionate (378-77-8)

Guidance literature:

With sodium trimethylsilanolate; In dichloromethane; at 25 ℃; for 1h;

DOI:10.1016/S0040-4039(01)81697-X

Reference yield: 89.0%

1,1,1-trichloropentafluoro-2-butanone (87375-47-1) → chloroform (67-66-3,8013-54-5) + sodium pentafluoropropionate (378-77-8)

Guidance literature:

With sodium hydroxide; In water; for 1h; Product distribution; Heating;

DOI:10.1007/BF01141717

upstream raw materials:

1,1,1,2,2,3,3-heptafluoro-3-iodo-propane

perfluoropropionic acid methyl ester

bis(pentafluoropropionyl)peroxide

sodium 2-nitropropane

Downstream raw materials:

1-nitro-4-(1,1,2,2,2-pentafluoroethyl)-benzene

o-chloropentafluoroethylbenzene

Chloropentafluoroethane

bromopentafluoroethane

Refernces

• 1、 Filyakova,Kodess,Zapevalov. "Synthesis and some properties of 1-chloro(bromo)heptafluoro-1-butenes and their epoxy derivatives". . p. 1256 - 1262. Retrieved 2007/10/03.
• 2、 Huang, Bing-Nan,Haas, A.,Lieb, M.. "A NEW METHOD FOR THE PREPARATION OF PERFLUOROCARBOXYLIC ACIDS". . p. 49 - 62. Retrieved 2007/10/02.