BICYCLO[3.2.1]-2-OCTENE

Base Information

• Chemical Name: BICYCLO[3.2.1]-2-OCTENE
• CAS No.: 823-02-9
• Molecular Formula: C₈H₁₂
• Molecular Weight: 108.183
• Mol file: 823-02-9.mol

Synonyms:NSC 76147;

Chemical Property of BICYCLO[3.2.1]-2-OCTENE

Chemical Property:

• Vapor Pressure: 8.41mmHg at 25°C
• Melting Point: 39°C
• Refractive Index: 1.506
• Boiling Point: 138.3 °C at 760 mmHg
• Flash Point: 18.5 °C
• PSA: 0.00000
• Density: 0.93 g/cm³
• LogP: 2.36260
• Solubility.: almost transparency in Methanol

Purity/Quality:

98%,99%, ^*data from raw suppliers

Bicyclo[3.2.1]-2-octene ^*data from reagent suppliers

Safty Information:

• Safety Statements: 23-24/25

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of BICYCLO[3.2.1]-2-OCTENE

There total 10 articles about BICYCLO[3.2.1]-2-OCTENE which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

ethyl N-nitroso-N-(bicyclo<3.2.1>octan-2-yl)carbamate (90893-13-3) → norbornene (931-64-6) + Bicyclo<3.2.1>oct-2-ene (823-02-9,61617-43-4,84235-38-1) + N-(bicyclo<2.2.2>octyl)aniline (93638-23-4) + tricyclo<3.2.1.02,7>octane (285-43-8) + (1R,3R,5S)-Bicyclo[3.2.1]oct-3-yl-phenyl-amine (93638-31-4) + N-(exo-bicyclo<3.2.1>oct-2-yl)aniline (93638-25-6,93638-27-8)

Guidance literature:

With ethanol; Product distribution; Mechanism; deamination reactions of amine via nitrosocarbamate;

DOI:10.1039/P29840000119

Reference yield:

ethyl N-nitroso-N-(exo-bicyclo<3.2.1>octan-2-yl)carbamate (90893-12-2,90893-14-4) → norbornene (931-64-6) + Bicyclo<3.2.1>oct-2-ene (823-02-9,61617-43-4,84235-38-1) + N-(bicyclo<2.2.2>octyl)aniline (93638-23-4) + tricyclo<3.2.1.02,7>octane (285-43-8) + (1S,3S,5R)-Bicyclo[3.2.1]oct-3-yl-phenyl-amine (93638-29-0) + N-(exo-bicyclo<3.2.1>oct-2-yl)aniline (93638-25-6,93638-27-8)

Guidance literature:

With ethanol; Product distribution; Mechanism; deamination reactions of amine via nitrosocarbamate;

DOI:10.1039/P29840000119

Reference yield:

5-chloromethyl-2-norbornene (95-09-0) → bicyclo[3.3.0]oct-2-ene (5549-09-7) + bicyclo[3.2.1]oct-2-ene (823-02-9,61617-43-4) + 4-allylcyclopentene (765-99-1) + 3-allyl-1-cyclopentene (14564-97-7)

Guidance literature:

With sodium; In various solvent(s); at 80 - 110 ℃; for 1h; Further byproducts given;

DOI:10.1021/jo00283a022

upstream raw materials:

2-Formyl-norbornan-p-toluolsulfonylhydrazon

5-chloromethyl-2-norbornene

acetic acid

1-phenyl-3-(exo-bicyclo<3.2.1>octan-3-yl)triazine

Downstream raw materials:

bicyclo[3.2.1]octane

bicyclo[3.2.1]octan-3-one

bicyclo[3.2.1]octan-2-one

endo-bicyclo<3.2.1>-octan-2-ol

Refernces

• 1、 Jennings, P. W.,Ekeland, R. E.,Waddington, M. D.,Hanks, T. W.. "TRANSFORMATIONS OF CYCLOPROPANE IN RIGID HYDROCARBON SYSTEMS USING PLATINUM(II)". . p. 429 - 436. Retrieved 2007/10/02.
• 2、 Maskill, Howard,Wilson, Alan A.. "DEAMINATION OF BICYCLOOCTAN-2-YL- AND BICYCLOOCTAN-2-YL-AMINES. EVIDENCE FOR CLASSICAL PRECURSORS OF NON-CLASSICAL CARBONIUM IONS". . p. 119 - 128. Retrieved 2007/10/02.