D-Glucose ethylenedithioacetal

Base Information

• Chemical Name: D-Glucose ethylenedithioacetal
• CAS No.: 3650-65-5
• Molecular Formula: C8H16O5S2
• Molecular Weight: 256.344
• Hs Code.: 29349990
• European Community (EC) Number: 222-889-6
• UNII: 6EB466KY92
• DSSTox Substance ID: DTXSID401250945
• Nikkaji Number: J109.438F
• Mol file: 3650-65-5.mol

Synonyms:3650-65-5;D-Glucose ethylenedithioacetal;D-Glucose cyclic ethylene dithioacetal;(1R,2S,3R,4R)-1-(1,3-dithiolan-2-yl)pentane-1,2,3,4,5-pentol;6EB466KY92;EINECS 222-889-6;D-GLUCOSE ETHYLENEDITHIOACETAL 97;D-Glucose, cyclic 1,2-ethanediyl dithioacetal;D-Glucose, ethylenedithioacetal;D-Glucose, cyclic 1,2-ethanediyl mercaptal;C8-H16-O5-S2;NSC-143003;C(O)(C1SCCS1)C(O)C(O)C(O)CO;1-(1,3-dithiolan-2-yl)pentane-1,2,3,4,5-pentol;UNII-6EB466KY92;D-Glucose ethylenedithioacetal 97;DTXSID401250945;MFCD00051981;AKOS015898541;D-Glucose, ethylenedithioacetal, 97%;1-Deoxo-1,1-ethylenedithio-D-glucose;NSC 143003;A823277;W-202516

Chemical Property of D-Glucose ethylenedithioacetal

Chemical Property:

• Appearance/Colour: white to light yellow crystal powder
• Vapor Pressure: 1.46E-18mmHg at 25°C
• Melting Point: 144-149 °C(lit.)
• Refractive Index: 1.677
• Boiling Point: 630.8 °C at 760 mmHg
• Flash Point: 305.3 °C
• PSA: 151.75000
• Density: 1.587 g/cm³
• LogP: -1.77160
• Storage Temp.: 2-8°C
• XLogP3: -1.7
• Hydrogen Bond Donor Count: 5
• Hydrogen Bond Acceptor Count: 7
• Rotatable Bond Count: 5
• Exact Mass: 256.04391595
• Heavy Atom Count: 15
• Complexity: 188

Purity/Quality:

99%min ^*data from raw suppliers

D-Glucose, ethylenedithioacetal 97% ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

• Canonical SMILES: C1CSC(S1)C(C(C(C(CO)O)O)O)O
• Isomeric SMILES: C1CSC(S1)[C@@H]([C@H]([C@@H]([C@@H](CO)O)O)O)O

Technology Process of D-Glucose ethylenedithioacetal

There total 2 articles about D-Glucose ethylenedithioacetal which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

D-glucose (50-99-7) + ethane-1,2-dithiol (540-63-6) → D-glucose ethylene dithioacetal (3650-65-5)

Guidance literature:

With hydrogenchloride; zinc(II) chloride;

Reference yield:

→ D-glucose ethylene dithioacetal (3650-65-5)

Guidance literature:

DOI:10.1021/jo01016a056

Reference yield: 90.0%

methanol (67-56-1) + D-glucose ethylene dithioacetal (3650-65-5) → methyl D-glucopyranoside (97-30-3,617-04-9,709-50-2,1824-94-8,2152-78-5,3396-99-4,6819-48-3,18469-06-2,20550-04-3,22277-65-2,29411-57-2,35437-40-2,35437-43-5,36191-11-4,36191-12-5,39598-79-3,39598-80-6,39598-89-5,51023-63-3,51223-62-2,51224-38-5,51224-39-6,51224-40-9,51224-41-0,51819-81-9,51819-82-0,51819-83-1,56688-81-4,62279-53-2,64281-79-4,64281-80-7,64912-19-2,66101-73-3,78184-90-4,84368-39-8,84368-40-1,84368-41-2,92142-37-5,93302-26-2,103421-28-9,115794-08-6,3149-68-6)

Guidance literature:

With iodine; for 18h; Heating;

DOI:10.1016/S0040-4039(00)83890-3

upstream raw materials:

D-glucose

ethane-1,2-dithiol

Downstream raw materials:

O⁶-(toluene-4-sulfonyl)-D-glucose-ethanediyldithioacetal

methyl D-glucopyranoside