Trichloro(hexadecyl)silane

Base Information

• Chemical Name: Trichloro(hexadecyl)silane
• CAS No.: 5894-60-0
• Molecular Formula: C16H33 Cl3 Si
• Molecular Weight: 359.883
• European Community (EC) Number: 227-575-2
• NSC Number: 22328
• UN Number: 1781
• UNII: VFL27Y3GTE
• DSSTox Substance ID: DTXSID10884196
• Nikkaji Number: J36.480K
• Wikidata: Q27291808
• Mol file: 5894-60-0.mol

Synonyms:hexadecyltrichlorosilane

Chemical Property of Trichloro(hexadecyl)silane

Chemical Property:

• Vapor Pressure: 1.17E-11mmHg at 25°C
• Melting Point: >20°C
• Refractive Index: n20/D 1.458
• Boiling Point: 202 °C
• Flash Point: 170.1°C
• PSA: 0.00000
• Density: 0.992g/cm³
• LogP: 8.12300
• Water Solubility.: 673g/L at 30℃
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 0
• Rotatable Bond Count: 14
• Exact Mass: 358.141711
• Heavy Atom Count: 20
• Complexity: 193
• Transport DOT Label: Corrosive

Purity/Quality:

99.9% ^*data from raw suppliers

Trichloro(hexadecyl)silane ^*data from reagent suppliers

Safty Information:

• Pictogram(s): Strong irritant. Combustible. Evolves hydrogen chloride in the presence of moisture.
• Hazard Codes: C
• Statements: 14-35
• Safety Statements: 26-28-36/37/39-45

MSDS Files:

SDS file from LookChem

Useful:

• Chemical Classes: Toxic Gases & Vapors -> Chlorosilanes
• Canonical SMILES: CCCCCCCCCCCCCCCC[Si](Cl)(Cl)Cl

Technology Process of Trichloro(hexadecyl)silane

There total 10 articles about Trichloro(hexadecyl)silane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

→ trichloro-hexadecyl-silane (5894-60-0) + n-dotriacontane (544-85-4)

Guidance literature:

With tetrachlorosilane; diethyl ether;

Reference yield:

1-Hexadecene (629-73-2) → trichloro-hexadecyl-silane (5894-60-0)

Guidance literature:

With trichlorosilane; at 300 ℃;

Reference yield:

1,5-dibromo-pentane (111-24-0) → trichloro-hexadecyl-silane (5894-60-0)

Guidance literature:

Multi-step reaction with 3 steps

1: Mg, Li₂CuCl₄

2: 70 percent / SiCl₃H / H₂PtCl₆

3: LiAlH₄ / diethyl ether

With lithium aluminium tetrahydride; dilithium tetrachlorocuprate; trichlorosilane; magnesium; dihydrogen hexachloroplatinate; In diethyl ether;

DOI:10.1016/S0040-4039(00)80820-5

upstream raw materials:

1-Hexadecene

1-bromo-16-(trichlorosilyl)hexadecane

1,5-dibromo-pentane

10-Undecen-1-ol

Downstream raw materials:

Hexadecyl-tri--silan

Hexadecyl-tri--silan

Hexadecyl-tri--silan

hexadecyltriethoxysilane

Refernces