1-(2,4-Dinitrophenyl)-4-phenylpyridinium chloride

Base Information

• Chemical Name: 1-(2,4-Dinitrophenyl)-4-phenylpyridinium chloride
• CAS No.: 26863-15-0
• Molecular Formula: C17H12 N3 O4 . Cl
• Molecular Weight: 357.753
• Hs Code.: 2933399090
• European Community (EC) Number: 248-068-2
• DSSTox Substance ID: DTXSID50884559
• Mol file: 26863-15-0.mol

Synonyms:1-(2,4-Dinitrophenyl)-4-phenylpyridinium chloride;26863-15-0;EINECS 248-068-2;N-(2,4-Dinitrophenyl)-4-phenylpyridinium chloride;Pyridinium, 1-(2,4-dinitrophenyl)-4-phenyl-, chloride;Pyridinium, 1-(2,4-dinitrophenyl)-4-phenyl-, chloride (1:1);C17H12N3O4.Cl;1-(2,4-dinitrophenyl)-4-phenylpyridin-1-ium chloride;SCHEMBL8068701;DTXSID50884559;C17-H12-N3-O4.Cl;A819182;1-(2,4-dinitrophenyl)-4-phenyl-pyridin-1-ium chloride

Chemical Property of 1-(2,4-Dinitrophenyl)-4-phenylpyridinium chloride

Chemical Property:

• Melting Point: 186-187 °C
• PSA: 95.52000
• LogP: 1.49710
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 5
• Rotatable Bond Count: 2
• Exact Mass: 357.0516336
• Heavy Atom Count: 25
• Complexity: 448

Purity/Quality:

98%Min ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C1=CC=C(C=C1)C2=CC=[N+](C=C2)C3=C(C=C(C=C3)[N+](=O)[O-])[N+](=O)[O-].[Cl-]

Technology Process of 1-(2,4-Dinitrophenyl)-4-phenylpyridinium chloride

There total 1 articles about 1-(2,4-Dinitrophenyl)-4-phenylpyridinium chloride which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 98.0%

p-phenylpyridine (939-23-1) + 1-chloro-2,4-dinitro-benzene (97-00-7) → N-(2',4'-dinitrophenyl)-4-phenylpyridinium chloride (26863-15-0)

Guidance literature:

In acetone; for 72h; Heating;

DOI:10.1016/S0968-0896(98)80027-8

Reference yield: 98.0%

N-(2',4'-dinitrophenyl)-4-phenylpyridinium chloride (26863-15-0) + 4-methoxy-aniline (104-94-9) → C18H16NO(1+)*Cl(1-)

Guidance literature:

In water; for 12h; Heating;

DOI:10.1016/j.tetlet.2007.09.009

Reference yield: 97.0%

N-(2',4'-dinitrophenyl)-4-phenylpyridinium chloride (26863-15-0) + Cyclopropylamine (765-30-0) → 1-cyclopropyl-4-phenylpyridinium chloride

Guidance literature:

In butan-1-ol; at 25 ℃; for 15h; Heating;

DOI:10.1016/S0968-0896(98)80027-8

upstream raw materials:

p-phenylpyridine

1-chloro-2,4-dinitro-benzene

Downstream raw materials:

p-phenylpyridine

Refernces

• 1、 Kassl, Christopher J.,Swenson, Dale C.,Pigge, F. Christopher. "Charge-Assisted Halogen Bonding in Bromo- and Iodophenylpyridinium Chlorides". . p. 4571 - 4580. Retrieved 2015/09/15.
• 2、 Steinhardt, Sarah E.,Vanderwal, Christopher D.. "Complex polycyclic lactams from pericyclic cascade reactions of Zincke aldehydes". supporting information; scheme or table. p. 7546 - 7547. Retrieved 2009/10/17.