Chlorozinc(1+) zinc 5,5-dimethyl-1,1,3,3-tetraphenyl-N-(trimethylsilyl)-4-aza-1lambda~5~,3lambda~5~-diphospha-5-silahexa-1,3-dien-2-id-1-aminide (2/1/2)

Base Information

• Chemical Name: Chlorozinc(1+) zinc 5,5-dimethyl-1,1,3,3-tetraphenyl-N-(trimethylsilyl)-4-aza-1lambda~5~,3lambda~5~-diphospha-5-silahexa-1,3-dien-2-id-1-aminide (2/1/2)
• CAS No.: 7234-76-6
• Molecular Formula: C₁₅H₁₃N
• Molecular Weight: 207.275
• DSSTox Substance ID: DTXSID50413262
• Mol file: 7234-76-6.mol

Synonyms:7234-76-6;DTXSID50413262;Chlorozinc(1+) zinc 5,5-dimethyl-1,1,3,3-tetraphenyl-N-(trimethylsilyl)-4-aza-1lambda~5~,3lambda~5~-diphospha-5-silahexa-1,3-dien-2-id-1-aminide (2/1/2);Zinc;chlorozinc(1+);[[diphenyl(trimethylsilylimino)-lambda5-phosphanyl]methylidene-diphenyl-lambda5-phosphanyl]-trimethylsilylazanide

Chemical Property of Chlorozinc(1+) zinc 5,5-dimethyl-1,1,3,3-tetraphenyl-N-(trimethylsilyl)-4-aza-1lambda~5~,3lambda~5~-diphospha-5-silahexa-1,3-dien-2-id-1-aminide (2/1/2)

Chemical Property:

• Vapor Pressure: 5.29E-15mmHg at 25°C
• Boiling Point: 613.8°C at 760 mmHg
• Flash Point: 325°C
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 6
• Rotatable Bond Count: 16
• Exact Mass: 1376.13178
• Heavy Atom Count: 79
• Complexity: 709

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C[Si](C)(C)[N-]P(=[C-]P(=N[Si](C)(C)C)(C1=CC=CC=C1)C2=CC=CC=C2)(C3=CC=CC=C3)C4=CC=CC=C4.C[Si](C)(C)[N-]P(=[C-]P(=N[Si](C)(C)C)(C1=CC=CC=C1)C2=CC=CC=C2)(C3=CC=CC=C3)C4=CC=CC=C4.Cl[Zn+].Cl[Zn+].[Zn+2]

Technology Process of Chlorozinc(1+) zinc 5,5-dimethyl-1,1,3,3-tetraphenyl-N-(trimethylsilyl)-4-aza-1lambda~5~,3lambda~5~-diphospha-5-silahexa-1,3-dien-2-id-1-aminide (2/1/2)

There total 4 articles about Chlorozinc(1+) zinc 5,5-dimethyl-1,1,3,3-tetraphenyl-N-(trimethylsilyl)-4-aza-1lambda~5~,3lambda~5~-diphospha-5-silahexa-1,3-dien-2-id-1-aminide (2/1/2) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 84.0%

(1R,2R)-cyclopentane-1,2-diol (930-46-1,86703-52-8) + 1-amino-naphthalene (134-32-7) → 7,8,9,10-tetrahydrobenzo[g]cyclopenta[b]indole (7234-76-6)

Guidance literature:

With iridium (III) chloride trihydrate; oxygen; sodium carbonate; triphenylphosphine; In 1,3,5-trimethyl-benzene; at 169 ℃; for 15h;

DOI:10.1021/jo801966u

Reference yield: 84.0%

Cyclopentene oxide (285-67-6) + 1-amino-naphthalene (134-32-7) → 7,8,9,10-tetrahydrobenzo[g]cyclopenta[b]indole (7234-76-6)

Guidance literature:

Cyclopentene oxide; 1-amino-naphthalene; With zinc trifluoromethanesulfonate; at 20 ℃; for 1h; Inert atmosphere;

With 1,1'-bis-(diphenylphosphino)ferrocene; dodecacarbonyl-triangulo-triruthenium; toluene-4-sulfonic acid; In 1,4-dioxane; at 150 ℃; for 22h; Inert atmosphere;

DOI:10.1002/chem.201304432

Reference yield: 55.0%

cyclopentanone (120-92-3) + 1-(1-naphthyl)hydrazine (2243-55-2) → 7,8,9,10-tetrahydrobenzo[g]cyclopenta[b]indole (7234-76-6)

Guidance literature:

With sodium acetate; acetic acid; In dichloromethane; water; for 2h; Reflux;

DOI:10.1016/j.dyepig.2011.02.009

upstream raw materials:

(1R,2R)-cyclopentane-1,2-diol

1-amino-naphthalene

cyclopentanone

1-(1-naphthyl)hydrazine

Downstream raw materials:

10-[4-(2,2-diphenylethenyl)phenyl]-6b,-7,8,9,9a,10-hexahydrobenzo[g]cyclopenta[b]indole

10-[4-(2,2-diphenylethenyl)phenyl]-6b,7,8,9,9a,10-hexahydrobenzo[g]cyclopenta[b]indole-5-carbaldehyde

Refernces

• 1、 Pena-Lopez, Miguel,Neumann, Helfried,Beller, Matthias. "Ruthenium-catalyzed synthesis of indoles from anilines and epoxides". supporting information. p. 1818 - 1824. Retrieved 2014/03/21.
• 2、 Aramoto, Hiroomi,Obora, Yasushi,Ishii, Yasutaka. "N-Heterocyclization of naphthylamines with 1,2- And 1,3-Diols catalyzed by an iridium Chloride/BINAP system". scheme or table. p. 628 - 633. Retrieved 2009/06/28.