Propyl 3-[chloro(dimethyl)silyl]-2-methylprop-2-enoate

Base Information

• Chemical Name: Propyl 3-[chloro(dimethyl)silyl]-2-methylprop-2-enoate
• CAS No.: 24636-31-5
• Molecular Formula: C9H17ClO2Si
• Molecular Weight: 220.771
• Hs Code.: 2931900090
• Mol file: 24636-31-5.mol

Synonyms:propyl 3-[chloro(dimethyl)silyl]-2-methylprop-2-enoate;UNII-PV77A3NAU2

Chemical Property of Propyl 3-[chloro(dimethyl)silyl]-2-methylprop-2-enoate

Chemical Property:

• Vapor Pressure: 0.0116mmHg at 25°C
• Refractive Index: n20/D 1.451
• Boiling Point: 261.324 °C at 760 mmHg
• Flash Point: 111.845 °C
• PSA: 26.30000
• Density: 0.992 g/cm³
• LogP: 2.93970
• Storage Temp.: below 5° C
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 2
• Rotatable Bond Count: 5
• Exact Mass: 220.0686340
• Heavy Atom Count: 13
• Complexity: 212

Purity/Quality:

99.9% ^*data from raw suppliers

3-(Chlorodimethylsilyl)propyl Methacrylate (stabilized with BHT) ^*data from reagent suppliers

Safty Information:

• Pictogram(s): C
• Hazard Codes: C
• Statements: 34
• Safety Statements: 26-27-36-45

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

• Canonical SMILES: CCCOC(=O)C(=C[Si](C)(C)Cl)C

Technology Process of Propyl 3-[chloro(dimethyl)silyl]-2-methylprop-2-enoate

There total 4 articles about Propyl 3-[chloro(dimethyl)silyl]-2-methylprop-2-enoate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 97.9%

dimethylmonochlorosilane (1066-35-9) + allyl methacrylate (96-05-9) → 3-Methacryloxypropyldimethylchlorosilane (24636-31-5)

Guidance literature:

dimethylmonochlorosilane; allyl methacrylate; With 10H-phenothiazine; platinum⁽⁰⁾-1,3-divinyl-1,1,3,3-tetramethyldisiloxane complex; In 5,5-dimethyl-1,3-cyclohexadiene; at 80 ℃; for 0.666667h; under 5171.62 Torr; Flow reactor; Sealed tube; Inert atmosphere;

With 2,6-di-tert-butyl-4-methyl-phenol; In 5,5-dimethyl-1,3-cyclohexadiene; at 80 ℃; for 1h; Temperature; Inert atmosphere;

Reference yield: 85.6%

dimethylmonochlorosilane (1066-35-9) + 1,1,3,3-Tetramethyldisiloxane (3277-26-7) + allyl methacrylate (96-05-9) → 3-Methacryloxypropyldimethylchlorosilane (24636-31-5)

Guidance literature:

With bis(1,5-cyclooctadiene)diiridium(I) dichloride; 2,6-di-tert-butyl-4-methyl-phenol; cyclo-octa-1,5-diene; at 60 - 70 ℃; for 1h; Inert atmosphere;

Reference yield:

2,2-dimethyl-1-oxa-2-silacyclopentane (3292-88-4) + Methacryloyl chloride (920-46-7,26937-45-1) → 3-Methacryloxypropyldimethylchlorosilane (24636-31-5)

Guidance literature:

With 10H-phenothiazine;

upstream raw materials:

2,2-dimethyl-1-oxa-2-silacyclopentane

Methacryloyl chloride

dimethylmonochlorosilane

allyl methacrylate

Downstream raw materials:

1,3-bis<3-(2-methylpropenoyloxy)propyl>tetramethyldisiloxane

<1-(2-methylpropenoyloxy)propyl>pentamethyldisiloxane

3-(acetoxydimethylsilyl)propyl methacrylate

acetyl chloride

Refernces

• 1、 -. "PROCESS FOR PRODUCING DIMETHYLCHLOROSILANE COMPOUND". Paragraph 0094; 0096. . Retrieved 2021/11/20.
• 2、 Cai, Lu,Li, Zhanxiong. "Synthesis and surface properties of novel fluoroalkylsilyl methacrylate copolymers". . p. 187 - 194. Retrieved 2015/08/19.