Methyl penta-2,4-dienoate

Base Information Edit

Chemical Name:Methyl penta-2,4-dienoate
CAS No.:1515-75-9
Molecular Formula:C6H8 O2
Molecular Weight:112.128
Hs Code.:29161995
European Community (EC) Number:216-158-0
Nikkaji Number:J276.818F,J206.720J
Wikidata:Q76313721
Mol file:1515-75-9.mol

Synonyms:Methyl penta-2,4-dienoate;1515-75-9;Methyl 1,3-butadiene-1-carboxylate;(E)-methyl penta-2,4-dienoate;2409-87-2;1,3-Butadiene-1-carboxylic acid methyl ester;methyl (2E)-penta-2,4-dienoate;Methyl 2,4-pentadienoate;EINECS 216-158-0;(2E)-2,4-PentadienoicAcidMethylEster;(2E)-2,4-Pentadienoic Acid Methyl Ester;2,4-Pentadienoic acid, methyl ester;methyl pentadienoate;Methylpenta-2,4-dienoate;1,3-BUTADIENE-1-CARBOXYLICACIDMETHYLESTER;SCHEMBL1408458;SCHEMBL1408587;Methyl (E)-2,4-pentadienoate;(E)-methyl-penta-2,4-dienoate;LJDLNNZTQJVBNJ-SNAWJCMRSA-N;BS-21539;(2E)-penta-2,4-dienoic acid methyl ester;LS-185519;E77965;W-109674

Suppliers and Price of Methyl penta-2,4-dienoate

Supply Marketing:Edit

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Sigma-Aldrich
Methyl 2,4-pentadienoate mixture of cis and trans, ≥97.0% (GC)
5ml
$ 132.00

American Custom Chemicals Corporation
METHYL 2,4-PENTADIENOATE 95.00%
5ML
$ 874.34

Total 12 raw suppliers

Chemical Property of Methyl penta-2,4-dienoate Edit

Chemical Property:

Vapor Pressure:7.8mmHg at 25°C
Refractive Index:n20/D 1.484
Boiling Point:135.2°Cat760mmHg
Flash Point:46.4°C
PSA：26.30000
Density:0.936g/cm³
LogP:0.90160
Storage Temp.:−20°C
XLogP3:1.4
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:2
Rotatable Bond Count:3
Exact Mass:112.052429494
Heavy Atom Count:8
Complexity:114

Purity/Quality:

98%,99%, ^*data from raw suppliers

Methyl 2,4-pentadienoate mixture of cis and trans, ≥97.0% (GC) ^*data from reagent suppliers

Safty Information:

Pictogram(s):
Hazard Codes:Xi
Statements: 10-36/37/38-52/53
Safety Statements: 26-36-61

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

Canonical SMILES:COC(=O)C=CC=C
Isomeric SMILES:COC(=O)/C=C/C=C

Technology Process of Methyl penta-2,4-dienoate

There total 7 articles about Methyl penta-2,4-dienoate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 63.0%

: 74-85-1
ethene

: 89123-62-6
Methyl 3-bromopropenoate

: 1515-75-9
methyl 2,4-pentadienoate

Guidance literature:: With 10H-phenothiazine; bis(μ-chloro)bis{(2-(1-(hydroxyimino)methyl)phenyl-C1,N)palladium(II)}; potassium acetate; In N,N-dimethyl acetamide; at 105 ℃; for 24h; under 775.743 Torr; Inert atmosphere;
DOI:10.1016/j.tet.2009.11.017

Reference yield: 20.0%

: 67-56-1
methanol

: 626-99-3
1,3-butadiene-1-carboxylic acid

: 1515-75-9
methyl 2,4-pentadienoate

Guidance literature:: With hydrogenchloride;

Reference yield:

: 38330-80-2
monomethyl monopotassium malonate

: 107-02-8,25068-14-8
acrolein

: 1515-75-9
methyl 2,4-pentadienoate

Guidance literature:: monomethyl monopotassium malonate; With pyridine; pyridine hydrochloride; In N,N-dimethyl-formamide; at 40 - 45 ℃; for 1.5h; Inert atmosphere;

acrolein; In N,N-dimethyl-formamide; at 25 - 35 ℃; for 25.8333h; Product distribution / selectivity;