bis(4-broMophenyl)-4-sec-butylaniline

Base Information

• Chemical Name: bis(4-broMophenyl)-4-sec-butylaniline
• CAS No.: 287976-94-7
• Molecular Formula: C22H21Br2N
• Molecular Weight: 459.21700
• Mol file: 287976-94-7.mol

Synonyms:

Chemical Property of bis(4-broMophenyl)-4-sec-butylaniline

Chemical Property:

• Boiling Point: 508.5±45.0 °C(Predicted)
• PKA: -3.99±0.60(Predicted)
• PSA: 3.24000
• Density: 1.437±0.06 g/cm3(Predicted)
• LogP: 8.19490
• Storage Temp.: under inert gas (nitrogen or Argon) at 2–8 °C

Purity/Quality:

99% ^*data from raw suppliers

4-Bromo-N-(4-bromophenyl)-N-(4-(sec-butyl)phenyl)aniline 98% ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of bis(4-broMophenyl)-4-sec-butylaniline

There total 4 articles about bis(4-broMophenyl)-4-sec-butylaniline which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 33.0%

1,4-bromoiodobenzene (589-87-7) + 4-sec-butylaniline (30273-11-1,181288-08-4) → 4-(3-methylpropyl)-N,N-bis(4-bromophenyl)aniline (287976-94-7)

Guidance literature:

With 1,10-Phenanthroline; copper(l) chloride; In water; toluene; for 20h; Reflux; Inert atmosphere; Dean-Stark conditions;

DOI:10.1039/c1jm11242b

Reference yield:

N,N-diphenyl-4-sec-butylphenylamine (423774-97-4) → 4-(3-methylpropyl)-N,N-bis(4-bromophenyl)aniline (287976-94-7)

Guidance literature:

With N-Bromosuccinimide; In N,N-dimethyl-formamide;

DOI:10.1002/pola.24432

Reference yield:

4-sec-butylaniline (30273-11-1,181288-08-4) → 4-(3-methylpropyl)-N,N-bis(4-bromophenyl)aniline (287976-94-7)

Guidance literature:

Multi-step reaction with 3 steps

1: sodium nitrite / water; hydrogenchloride / liquid HCl

2: palladium diacetate / hexane; toluene

3: N-Bromosuccinimide / water; N,N-dimethyl-formamide

With N-Bromosuccinimide; palladium diacetate; sodium nitrite; In hydrogenchloride; hexane; water; N,N-dimethyl-formamide; toluene;

upstream raw materials:

1,4-bromoiodobenzene

4-sec-butylaniline

bromobenzene

N,N-diphenyl-4-sec-butylphenylamine

Refernces

• 1、 -. "POLYMERS, THEIR PREPARATION AND USES". Page/Page column. . Retrieved 2014/08/20.