COPPER(I) ACETATE

Base Information

• Chemical Name: COPPER(I) ACETATE
• CAS No.: 598-54-9
• Molecular Formula: C₂H₃O₂*Cu
• Molecular Weight: 122.591
• Hs Code.: 29152900
• Mol file: 598-54-9.mol

Synonyms:Aceticacid, copper(1+) salt (8CI,9CI);Copper acetate (CuOAc) (6CI);Coppermonoacetate;Copper(1+) acetate;Copper(I) acetate;Cuprous acetate;

Chemical Property of COPPER(I) ACETATE

Chemical Property:

• Appearance/Colour: Pale green or khaki powder
• Melting Point: 250 °C (dec.)(lit.)
• Boiling Point: decomposes if strongly heated [MER06]
• PSA: 26.30000
• LogP: 0.01130
• Storage Temp.: Keep in dark place,Inert atmosphere,Room temperature
• Sensitive.: moisture sensitive
• Water Solubility.: rapidly hydrolyzed by H2O to form yellow Cu2O [MER06]

Purity/Quality:

98%,99%, ^*data from raw suppliers

Copper(I) acetate ^*data from reagent suppliers

Safty Information:

• Pictogram(s): Xi
• Hazard Codes: Xi
• Statements: 36/37/38
• Safety Statements: 26-37/39

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

• Uses: Copper acetate(CuOAc) was used as a starting material for the preparation of copper nanoparticles and CuAlO2 p-type nanostructured semiconductors.

Technology Process of COPPER(I) ACETATE

There total 28 articles about COPPER(I) ACETATE which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 70.0%

→ tert-butyl peroxyacetate (107-71-1) + copper (I) acetate (598-54-9,142-71-2,4180-12-5,24381-58-6,66760-61-0,66760-62-1)

Guidance literature:

Reference yield: 65.0%

stannous octoate + copper diacetate (142-71-2) → Sn(4+)*2CH3(CH2)3CH(C2H5)COO(1-)*2CH3COO(1-)=Sn(CH3(CH2)3CH(C2H5)COO)2(CH3COO)2 + copper (I) acetate (598-54-9,142-71-2,4180-12-5,24381-58-6,66760-61-0,66760-62-1)

Guidance literature:

In dichloromethane; mixt. of copper(II) acetate and tin(II) 2-ethylhexanoate in CH2Cl2 is stirred at room temp. for 4 h; filtration, product is washed with CH2Cl2, solid dried in vacuo for several hours; elem. anal.;

DOI:10.1016/S0277-5387(00)84170-4

Reference yield: 63.0%

acetic acid (64-19-7,77671-22-8) + copper(l) chloride → copper (I) acetate (598-54-9,142-71-2,4180-12-5,24381-58-6,66760-61-0,66760-62-1)

Guidance literature:

With triethylamine; In dichloromethane; (N2); CH3COOH added to a suspn. of CuCl at 25°C, stirred for 10 min, a soln. of (C2H5)3N added, stirred at 25°C for 5 h; filtered off, washed (CH2Cl2), dried (vac.);

DOI:10.1002/zaac.200800189

upstream raw materials:

copper diacetate

acetic acid

ammonium acetate

copper(II) acetate monohydrate

Downstream raw materials:

4,5-difluoro-2-[[1-(2-pyridinyl)-1H-pyrazol-5-yl]amino]benzoic acid

4-chloro-3-ethyl-6,7-difluoro-1-(2-pyridinyl)-1H-pyrazolo[3,4-b]quinoline

4,5-difluoro-2-[[3-ethyl-1-(2-pyridinyl)-1H-pyrazol-5-yl]amino]benzoic acid

4-chloro-6,7-difluoro-3-methyl-1-(3-pyridinyl)-1H-pyrazolo[3,4-b]quinoline

Refernces

• 1、 Biedermann, Ralf,Kluge, Oliver,Fuhrmann, Daniel,Krautscheid, Harald. "Synthesis and crystal structures of [(iPr3P)2Cu(μ- ESiMe3)(InMe3)] (E = S, Se): Lewis acid-base adducts with chalcogen atoms in planar coordination". . p. 4727 - 4731. Retrieved 2013/09/24.
• 2、 Jakob, Alexander,Shen, Yingzhong,Waechtler, Thomas,Schulz, Stefan E.,Gessner, Thomas,Riedel, Ralf,Fasel, Claudia,Lang, Heinrich. "Copper(I) carboxylates of type [(nBu3P) mCuO2CR] (m = 1, 2, 3) - Synthesis, properties, and their use as CVD precursors". . p. 2226 - 2234. Retrieved 2009/05/08.