Anthracene, 9-[1,1'-biphenyl]-2-yl-10-bromo-

Base Information

• Chemical Name: Anthracene, 9-[1,1'-biphenyl]-2-yl-10-bromo-
• CAS No.: 400607-16-1
• Molecular Formula: C26H17Br
• Molecular Weight: 409.325
• Mol file: 400607-16-1.mol

Synonyms:Anthracene, 9-[1,1-biphenyl]-2-yl-10-bromo-;

Chemical Property of Anthracene, 9-[1,1'-biphenyl]-2-yl-10-bromo-

Chemical Property:

• Melting Point: 146.0 to 150.0 °C
• Boiling Point: 508.6±19.0 °C(Predicted)
• PSA: 0.00000
• Density: 1.344±0.06 g/cm3(Predicted)
• LogP: 8.08950
• Solubility.: soluble in Toluene

Purity/Quality:

99% ^*data from raw suppliers

9-Bromo-10-(2-phenylphenyl)anthracene ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of Anthracene, 9-[1,1'-biphenyl]-2-yl-10-bromo-

There total 6 articles about Anthracene, 9-[1,1'-biphenyl]-2-yl-10-bromo- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 91.0%

→ 9-([1,1′-biphenyl]-2-yl)-10-bromoanthracene (400607-16-1)

Guidance literature:

With N-Bromosuccinimide; In N,N-dimethyl-formamide; at 20 ℃; for 8h; Inert atmosphere;

Reference yield: 90.0%

9‐([1,1'‐biphenyl]‐2‐yl)anthracene (849223-96-7) → 9-([1,1′-biphenyl]-2-yl)-10-bromoanthracene (400607-16-1)

Guidance literature:

With N-Bromosuccinimide; In chloroform; N,N-dimethyl-formamide; at 40 ℃; for 12h; Inert atmosphere;

Reference yield:

2-Bromobiphenyl (2052-07-5) → 9-([1,1′-biphenyl]-2-yl)-10-bromoanthracene (400607-16-1)

Guidance literature:

Multi-step reaction with 3 steps

1.1: n-butyllithium / hexane; tetrahydrofuran / -78 °C

1.2: -78 - 20 °C

2.1: sodium carbonate / tetrakis(triphenylphosphine) palladium⁽⁰⁾ / toluene; water / 3 h / 100 °C

3.1: N-Bromosuccinimide / dichloromethane / 2 h / 20 °C / Darkness

With N-Bromosuccinimide; n-butyllithium; sodium carbonate; tetrakis(triphenylphosphine) palladium⁽⁰⁾; In tetrahydrofuran; hexane; dichloromethane; water; toluene;

upstream raw materials:

2-Bromobiphenyl

2‐{[1,1'‐biphenyl]‐2‐yl}‐4,4,5,5‐tetramethyl‐1,3,2‐dioxaborolane

9‐([1,1'‐biphenyl]‐2‐yl)anthracene

anthracene-9-boronic acid

Downstream raw materials:

C₇₃H₅₀

C₇₉H₅₄

10-([1,1'-biphenyl]-2-yl)-9-anthracenylboronic acid

C₃₂H₂₉BO₂

Refernces

• 1、 -. "Novel compound and organic light emitting device comprising the same". Paragraph 0158; 0163-0165; 0171-0173. . Retrieved 2021/03/09.
• 2、 -. "Naphthyl benzofuran and anthracene derivative, preparation method and application thereof and device". . . Retrieved 2018/07/10.